1-Bromo-2-iodo-3-methoxybenzene

Base Information

Chemical Name:1-Bromo-2-iodo-3-methoxybenzene
CAS No.:450412-22-3
Molecular Formula:C7H6BrIO
Molecular Weight:312.933
Hs Code.:2909309090
DSSTox Substance ID:DTXSID20434303
Nikkaji Number:J1.780.439A
Wikidata:Q82248670
Mol file:450412-22-3.mol

Synonyms:1-Bromo-2-iodo-3-methoxybenzene;450412-22-3;3-Bromo-2-iodoanisole;MFCD18089327;2-Iodo-3-bromoanisole;SCHEMBL4054307;DTXSID20434303;AB91660;DS-13981;SY101796;CS-0097746;O10381;A872432;AS-813/43501657

Suppliers and Price of 1-Bromo-2-iodo-3-methoxybenzene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
3-Bromo-2-iodoanisole
250mg
$ 150.00

SynQuest Laboratories
3-Bromo-2-iodoanisole
5 g
$ 196.00

SynQuest Laboratories
3-Bromo-2-iodoanisole
1 g
$ 50.00

Oakwood
3-Bromo-2-iodoanisole
1g
$ 29.00

Crysdot
1-Bromo-2-iodo-3-methoxybenzene 95+%
10g
$ 204.00

Chemenu
1-Bromo-2-iodo-3-methoxybenzene 95%
5g
$ 327.00

Biosynth Carbosynth
1-Bromo-2-iodo-3-methoxybenzene
2 g
$ 765.00

Biosynth Carbosynth
1-Bromo-2-iodo-3-methoxybenzene
1 g
$ 450.00

Biosynth Carbosynth
1-Bromo-2-iodo-3-methoxybenzene
500 mg
$ 260.00

Biosynth Carbosynth
1-Bromo-2-iodo-3-methoxybenzene
100 mg
$ 75.00

Total 21 raw suppliers

Chemical Property of 1-Bromo-2-iodo-3-methoxybenzene

Chemical Property:

Melting Point:63-65 °C
Boiling Point:287.1±25.0 °C(Predicted)
PSA：9.23000
Density:2.062±0.06 g/cm3(Predicted)
LogP:3.06230
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
XLogP3:3.2
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:311.86467
Heavy Atom Count:10
Complexity:110

Purity/Quality:

97% ^*data from raw suppliers

3-Bromo-2-iodoanisole ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C(C(=CC=C1)Br)I

Technology Process of 1-Bromo-2-iodo-3-methoxybenzene

There total 4 articles about 1-Bromo-2-iodo-3-methoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 2398-37-0
3-methoxyphenyl bromide

: 450412-22-3
1-bromo-2-iodo-3-methoxybenzene

Guidance literature:: 3-methoxyphenyl bromide; With tBu₂Zn(TMP)Li; In tetrahydrofuran; at -30 ℃; for 12h;

With iodine; In tetrahydrofuran; at 20 ℃; Further stages.;
DOI:10.1021/ja0202199

Reference yield:

: 863870-72-8
O-3-bromophenyl N,N-diethylcarbamate

: 450412-22-3
1-bromo-2-iodo-3-methoxybenzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: LDA / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: 84 percent / I₂ / tetrahydrofuran; hexane / -78 - 20 °C

2.1: NaOH / ethanol / Heating

3.1: 2.50 g / K₂CO₃ / acetonitrile / Heating

With sodium hydroxide; potassium carbonate; lithium diisopropyl amide; In tetrahydrofuran; ethanol; hexane; acetonitrile;
DOI:10.1021/jo070643y

Reference yield:

: 863870-79-5
O-3-bromo-2-iodophenyl N,N-diethylcarbamate

: 450412-22-3
1-bromo-2-iodo-3-methoxybenzene

Guidance literature:: Multi-step reaction with 2 steps

1: NaOH / ethanol / Heating

2: 2.50 g / K₂CO₃ / acetonitrile / Heating

With sodium hydroxide; potassium carbonate; In ethanol; acetonitrile;
DOI:10.1021/jo070643y