3-BUTENYLZINC BROMIDE

Base Information

Chemical Name:3-BUTENYLZINC BROMIDE
CAS No.:226570-67-8
Molecular Formula:C₄H₇BrZn
Molecular Weight:200.394
Hs Code.:
Mol file:226570-67-8.mol

Synonyms:3-BUTENYLZINC BROMIDE;3-Butenylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles;3-Butenylzinc bromide solution;3-Butenylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™

Suppliers and Price of 3-BUTENYLZINC BROMIDE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
But-3-enylzincbromide 0.50MinTHF97%
100ml
$ 562.00

Matrix Scientific
But-3-enylzincbromide 0.50MinTHF97%
50ml
$ 380.00

Matrix Scientific
But-3-enylzincbromide 0.50MinTHF97%
500ml
$ 1426.00

American Custom Chemicals Corporation
3-BUTENYLZINC BROMIDE 95.00%
1L
$ 6770.00

American Custom Chemicals Corporation
3-BUTENYLZINC BROMIDE 95.00%
500ML
$ 3585.00

American Custom Chemicals Corporation
3-BUTENYLZINC BROMIDE 95.00%
100ML
$ 1037.00

American Custom Chemicals Corporation
3-BUTENYLZINC BROMIDE 95.00%
50ML
$ 793.00

Total 4 raw suppliers

Chemical Property of 3-BUTENYLZINC BROMIDE

Chemical Property:

Flash Point:-21 °C
PSA：0.00000
LogP:-1.60190
Storage Temp.:2-8°C
Sensitive.:Air Sensitive

Purity/Quality:

97% ^*data from raw suppliers

But-3-enylzincbromide 0.50MinTHF97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:F,Xn
Statements: 11-19-22-36/37-40
Safety Statements: 16-26-36/37

MSDS Files:: SDS file from LookChem

Useful:

Uses Nucleophlic reagent applicable for substitution and addition reactions. Also could be used in cross coupling reactions (Negishi couplings).technical-documents

Technology Process of 3-BUTENYLZINC BROMIDE

There total 2 articles about 3-BUTENYLZINC BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7051-34-5
cyclopropylcarbinyl bromide

: 7440-66-6
zinc

: 226570-67-8
(but-3-en-1-yl)zinc(II) bromide

Guidance literature:: In tetrahydrofuran; byproducts: CH2CHCH2CH3; molar ratio Zn:org. molecule = 2:1, 0°C; centrifugation, detd. by (1)H-NMR spectroscopy;
DOI:10.1021/ja9844478

Reference yield:

: 5162-44-7
1-bromo-4-butene

: 7440-66-6
zinc

: 226570-67-8
(but-3-en-1-yl)zinc(II) bromide

Guidance literature:: With iodine; In N,N-dimethyl acetamide; at 80 ℃; Schlenk technique; Inert atmosphere; Sealed tube;
DOI:10.1021/acs.joc.8b02201

Reference yield:

: 226570-67-8
(but-3-en-1-yl)zinc(II) bromide

: 852546-91-9
N-phenyl-1-(2-vinylphenyl)methanimine

: 50824-05-0
4-trifluoromethoxybenzyl bromide

: C₂₇H₂₆F₃NO

Guidance literature:: With bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; In tetrahydrofuran; toluene; at 40 ℃; for 6h; regioselective reaction; Inert atmosphere; Sealed tube;
DOI:10.1021/jacs.0c09778 DOI:10.1021/jacs.1c06574