ferrocene

Base Information

• Chemical Name: ferrocene
• CAS No.: 55404-68-7
• Molecular Formula: C10Fe
• Molecular Weight: 0
• Mol file: 55404-68-7.mol

Synonyms:Di(cyclopentadienyl)iron; Ferrocene-d10; FerroceneBiscyclopentadienyliron; Bis(cyclopentadienyl)iron; iron(2+) dicyclopenta-2,4-dienide; cyclopenta-1,3-diene; iron; cyclopenta-1,3-diene; dicyclopenta-1,3-dien-1-yliron; Iron dicyclopentadienyl

Chemical Property of ferrocene

Chemical Property:

• Melting Point: 173-174oC
• Boiling Point: 249oC
• PSA: 0.00000
• LogP: 0.68170
• Water Solubility.: practically insoluble

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Hazard Codes: F:Flammable;;
• Statements: R11:; R22:; R51/53:
• Safety Statements: S22:; S61:

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ferrocene

There total 393 articles about ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li (59501-96-1) + (C5H5)Fe[P(OC6H5)3]2Cl (84430-52-4) → ferrocene (102-54-5,55404-68-7) + bis(phenylthio)methane (3561-67-9) + 1,2-bis(phenylthio)ethane (622-20-8) + diphenyldisulfane (882-33-7) + lithium chloride

Guidance literature:

In tetrahydrofuran; mixing reactants in THF at -78°C, slow warming to room temp. / further products; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;

DOI:10.1016/S0022-328X(00)86902-8

Reference yield: 98.0%

ferrocenium hexafluorophosphate + tetra-n-butylammonium tetramethylaurate(III) → ferrocene (102-54-5,55404-68-7) + gold (7440-57-5,457905-15-6)

Guidance literature:

In acetonitrile; byproducts: CH4, C2H6; inert atmosphere;

DOI:10.1021/om990043s

Reference yield: 97.0%

ferrocenium hexafluorophosphate + tetrabutylammonium dimethylaurate(I) (228118-52-3) → ferrocene (102-54-5,55404-68-7) + gold (7440-57-5,457905-15-6)

Guidance literature:

In tetrahydrofuran; byproducts: CH4, C2H6; He-atmosphere; addn. of 1 equiv. of Cp2FePF6 to soln. of aurate at -196°C, warming to room temp.;

DOI:10.1021/om990043s

upstream raw materials:

cyclopenta-1,3-diene

ferrocenyl-pentacarbonylmanganese

acetonitrile

(pentadeuteriocyclopentadienyl)[1,2,4-tris(trimethylsilyl)cyclopentadienyl]iron(II)

Downstream raw materials:

η-biphenyl-η-cyclopentadienyliron(II) hexafluorophosphate

ferrocenium

triiodide^(1-)

chloroferrocene

Refernces

• 1、 -. "Photoresist based on metallocene compound and preparation method and application thereof". Paragraph 0067; 0073; 0076-0077. . Retrieved 2021/05/26.
• 2、 Kadari, Lingaswamy,Erb, William,Roisnel, Thierry,Radha Krishna, Palakodety,Mongin, Florence. "Iodoferrocene as a partner inN-arylation of amides". . p. 15928 - 15941. Retrieved 2020/10/08.