3-Cyclohexene-1-carboxylicacid,1-hydroxy-,methylester,(1S)-(9CI)

Base Information

Chemical Name:3-Cyclohexene-1-carboxylicacid,1-hydroxy-,methylester,(1S)-(9CI)
CAS No.:290306-18-2
Molecular Formula:C8H12O3
Molecular Weight:156.181
Hs Code.:
Mol file:290306-18-2.mol

Synonyms:3-Cyclohexene-1-carboxylicacid,1-hydroxy-,methylester,(1S)-(9CI)

Suppliers and Price of 3-Cyclohexene-1-carboxylicacid,1-hydroxy-,methylester,(1S)-(9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of 3-Cyclohexene-1-carboxylicacid,1-hydroxy-,methylester,(1S)-(9CI)

Chemical Property:

PSA：46.53000
LogP:0.63060

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 3-Cyclohexene-1-carboxylicacid,1-hydroxy-,methylester,(1S)-(9CI)

There total 4 articles about 3-Cyclohexene-1-carboxylicacid,1-hydroxy-,methylester,(1S)-(9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 67-56-1
methanol

: 338734-63-7
(2R,5S)-2-(tert-butyl)-2-methyl-1,3-dioxaspiro[4.5]dec-7-en-4-one

: 290306-18-2
(1S)-hydroxy-cyclohex-3-ene carboxylic acid methyl ester

Guidance literature:: With hydrogenchloride; Heating;
DOI:10.1002/1522-2675(20000705)83:7<1625::AID-HLCA1625>3.0.CO;2-W

Reference yield:

: 933-38-0
(1S)-hydroxy-cyclohex-3-ene carboxylic acid

: 74-88-4
methyl iodide

: 290306-18-2
(1S)-hydroxy-cyclohex-3-ene carboxylic acid methyl ester

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 25 ℃; optical yield given as %ee;
DOI:10.1002/anie.200801424

Reference yield:

: 5-but-3-enyl-2-tert-butyl-2-methyl-[1,3]dioxolan-4-one

: 290306-18-2
(1S)-hydroxy-cyclohex-3-ene carboxylic acid methyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: KHMDS; HMPA / tetrahydrofuran; toluene / -78 °C

2: 94 percent / Grubbs catalyst / benzene / 25 °C

3: 98 percent / HCl / Heating

With hydrogenchloride; N,N,N,N,N,N-hexamethylphosphoric triamide; potassium hexamethylsilazane; Grubbs catalyst first generation; In tetrahydrofuran; toluene; benzene; 1: Alkylation / 2: Cyclization / 3: Hydrolysis;
DOI:10.1002/1522-2675(20000705)83:7<1625::AID-HLCA1625>3.0.CO;2-W