Bis(2,2'-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate)

Base Information

• Chemical Name: Bis(2,2'-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate)
• CAS No.: 84537-86-0
• Molecular Formula: C32F12H25N7P2Ru1
• Molecular Weight: 898.59
• DSSTox Substance ID: DTXSID30477241
• Mol file: 84537-86-0.mol

Synonyms:84537-86-0;Bis(2,2'-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate);Ru(bpy)2(phen-5-NH2)(PF6)2;146441-73-8;BIS(BIPYRIDINE)-(5-AMINOPHENANTHROLINE)R;1,10-phenanthrolin-5-amine;2-pyridin-2-ylpyridine;ruthenium(2+);dihexafluorophosphate;DTXSID30477241;Bis(2,2/'-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate);Bis(2,2'-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate), BioReagent, suitable for fluorescence

Chemical Property of Bis(2,2'-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate)

Chemical Property:

• Melting Point: 196 °C
• PSA: 130.54000
• LogP: 13.99840
• Storage Temp.: −20°C
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 21
• Rotatable Bond Count: 2
• Exact Mass: 899.049846
• Heavy Atom Count: 54
• Complexity: 414

Purity/Quality:

99% ^*data from raw suppliers

Bis(2,2′-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate) BioReagent, suitable for fluorescence ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC2=CC(=C3C=CC=NC3=C2N=C1)N.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Ru+2]

Technology Process of Bis(2,2'-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate)

There total 3 articles about Bis(2,2'-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

cis-dichloro(2,2′-bipyridine)ruthenium(II)chloride + ammonium hexafluorophosphate + 1,10-phenanthroline-5-amine (54258-41-2) → bis(2,2′-bipyridine)(5-aminophenanthroline)ruthenium bis(hexafluorophosphate) (84537-86-0)

Guidance literature:

cis-dichloro(2,2′-bipyridine)ruthenium(II)chloride; 1,10-phenanthroline-5-amine; In methanol; for 12h; Inert atmosphere; Reflux;

ammonium hexafluorophosphate; In methanol; water; for 0.166667h; Inert atmosphere;

DOI:10.1039/c3cc49171d

Reference yield:

ammonium hexafluorophosphate + 1,10-phenanthroline-5-amine (54258-41-2) + Ru(2,2'-bipyridine)2Cl2 → bis(2,2′-bipyridine)(5-aminophenanthroline)ruthenium bis(hexafluorophosphate) (84537-86-0)

Guidance literature:

1,10-phenanthroline-5-amine; Ru(2,2'-bipyridine)2Cl₂; With lithium chloride; In ethanol; water; at 110 ℃; for 8h; Inert atmosphere;

ammonium hexafluorophosphate; Inert atmosphere;

DOI:10.1039/c6ra02917e

Reference yield:

ammonium hexafluorophosphate + 1,10-phenanthroline-5-amine (54258-41-2) + bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate → bis(2,2′-bipyridine)(5-aminophenanthroline)ruthenium bis(hexafluorophosphate) (84537-86-0)

Guidance literature:

1,10-phenanthroline-5-amine; bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate; In ethanol; for 15h; Inert atmosphere; Reflux;

ammonium hexafluorophosphate; In water;

DOI:10.1039/c4dt02461c

upstream raw materials:

1,10-phenanthroline-5-amine

Downstream raw materials:

bis(2,2'-bipyridine)-5-(2,5-dimethoxyphenyl)acetylamino-1,10-phenanthroline ruthenium(II) hexafluorophosphate

RuP₃DMB

RuP₂DMB

RuP₄DMB

Refernces

• 1、 Lu, Dongdong,Gai, Fangyuan,Qiao, Zhen-An,Wang, Xue,Wang, Tao,Liu, Yunling,Huo, Qisheng. "Ru(bpy)2(phen-5-NH2)2+ doped ultrabright and photostable fluorescent silica nanoparticles". . p. 51591 - 51597. Retrieved 2016.