Dipropyl tartrate

Base Information

• Chemical Name: Dipropyl tartrate
• CAS No.: 4181-80-0
• Molecular Formula: C10H18O6
• Molecular Weight: 234.249
• Hs Code.: 2918130000
• European Community (EC) Number: 218-708-5,224-054-1
• DSSTox Substance ID: DTXSID40870946
• Nikkaji Number: J224.980D
• Mol file: 4181-80-0.mol

Synonyms:Dipropyl tartrate;dipropyltartrat;4181-80-0;Dipropyl 2,3-dihydroxybutanedioate (R-(R*,R*))-;EINECS 218-708-5;EINECS 224-054-1;AI3-32466;2217-14-3;Tartaric acid dipropyl ester;Butanedioic acid, 2,3-dihydroxy- (R-(R*,R*))-, dipropyl ester;SCHEMBL2866836;DTXSID40870946;Butanedioic acid, 2,3-dihydroxy-, dipropyl ester, (R-(R*,R*))-

Chemical Property of Dipropyl tartrate

Chemical Property:

• Vapor Pressure: 9.21E-05mmHg at 25°C
• Boiling Point: 303°Cat760mmHg
• Flash Point: 111.7°C
• PSA: 93.06000
• Density: 1.193g/cm³
• LogP: -0.38540
• XLogP3: 0.8
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 9
• Exact Mass: 234.11033829
• Heavy Atom Count: 16
• Complexity: 203

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCOC(=O)C(C(C(=O)OCCC)O)O

Technology Process of Dipropyl tartrate

There total 4 articles about Dipropyl tartrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.1%

propan-1-ol (71-23-8) + tartaric acid (87-69-4,138508-61-9) → tartaric acid dipropyl ester (4181-80-0)

Guidance literature:

With 3H⁽¹⁺⁾*O₄₀SiW₁₂^(4-)*C₂₁H₂₂O₃PS⁽¹⁺⁾; Reflux; Dean-Stark;

DOI:10.1007/s11696-019-00693-1

Reference yield: 76.5%

propan-1-ol (71-23-8) + tartaric acid (87-69-4,138508-61-9) → C7H12O6 + tartaric acid dipropyl ester (4181-80-0)

Guidance literature:

With toluene-4-sulfonic acid; for 10h; Reflux;

DOI:10.14233/ajchem.2013.14780

Reference yield:

propan-1-ol (71-23-8) + DL-tartaric acid (133-37-9,138508-61-9) → tartaric acid dipropyl ester (4181-80-0)

Guidance literature:

With hydrogenchloride;

upstream raw materials:

propan-1-ol

DL-tartaric acid

tartaric acid

Downstream raw materials:

1-nitro-1-phenylmethane

Refernces

• 1、 Portnova,Yamshchikova, Yu. F.,Krasnykh. "Retention Characteristics and Sorption Enthalpies of Esters of Natural Hydroxycarboxylic Acids on DB-1 Stationary Phase". . p. 577 - 583. Retrieved 2019/06/03.