d-Tartaric acid

Base Information

• Chemical Name: d-Tartaric acid
• CAS No.: 133-37-9
• Deprecated CAS: 1150316-16-7
• Molecular Formula: C4H6O6
• Molecular Weight: 150.088
• Hs Code.: 29181200
• European Community (EC) Number: 205-695-6
• ICSC Number: 0772
• UNII: RRX6A4PL3C
• DSSTox Substance ID: DTXSID4043775,DTXSID5046986
• Nikkaji Number: J9.264I
• Wikipedia: Tartaric acid,Tartaric_acid,Tartrate
• Wikidata: Q23034947
• NCI Thesaurus Code: C47744
• RXCUI: 37578
• Metabolomics Workbench ID: 44098
• ChEMBL ID: CHEMBL1200861
• Mol file: 133-37-9.mol

Synonyms:(R*,R*)-(+-)-2,3-dihydroxybutanedioic acid, monoammonium monosodium salt;aluminum tartrate;ammonium tartrate;calcium tartrate;calcium tartrate tetrahydrate;Mn(III) tartrate;potassium tartrate;seignette salt;sodium ammonium tartrate;sodium potassium tartrate;sodium tartrate;stannous tartrate;tartaric acid;tartaric acid, ((R*,R*)-(+-))-isomer;tartaric acid, (R*,S*)-isomer;tartaric acid, (R-(R*,R*))-isomer;tartaric acid, (S-(R*,R*))-isomer;tartaric acid, ammonium sodium salt, (1:1:1) salt, (R*,R*)-(+-)-isomer;tartaric acid, calcium salt, (R-R*,R*)-isomer;tartaric acid, monoammonium salt, (R-(R*,R*))-isomer;tartrate

Chemical Property of d-Tartaric acid

Chemical Property:

• Appearance/Colour: white crystalline powder
• Vapor Pressure: 4.93E-08mmHg at 25°C
• Melting Point: 210-212 °C(lit.)
• Refractive Index: 1.585
• Boiling Point: 399.3 °C at 760 mmHg
• PKA: 3.03, 4.37(at 25℃)
• Flash Point: 209.4 °C
• PSA: 115.06000
• Density: 1.886 g/cm³
• LogP: -2.12260
• Storage Temp.: Store below +30°C.
• Solubility.: H2O: 0.1 g/mL, clear
• Water Solubility.: soluble
• XLogP3: -1.9
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 150.01643791
• Heavy Atom Count: 10
• Complexity: 134

Purity/Quality:

98% ^*data from raw suppliers

DL-Tartaric acid ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-41
• Safety Statements: 26-37/39-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Other Classes -> Organic Acids
• Canonical SMILES: C(C(C(=O)O)O)(C(=O)O)O
• Isomeric SMILES: [C@H]([C@@H](C(=O)O)O)(C(=O)O)O
• Recent NIPH Clinical Trials: Unraveling of neural basis of voluntary cough and cough reflex
• Inhalation Risk: Evaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
• Effects of Short Term Exposure: Corrosive. The substance is corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Inhalation of the aerosol may cause lung oedema. The effects may be delayed. Medical observation is indicated.
• DESCRIPTION: Colourless or translucent crystals, or a white crystalline powder; odourless
• Uses: DL-Tartaric acid is used as a synergist for antioxidants, emulsifier, sequestrant and flavoring agent. It is also added with citric acid to prepare effervescent salts, thereby enhancing the taste of oral medications. It is also utilized in pigments, processing aids, ink, toner and colorant products. It acts as a chelating agent in metal and farming industries. Further, it is used as lubricant and grease. It is mixed with sodium bicarbonate and used as a leavening agent in food preparation. In the pharmaceutical industry, it is utilized in the preparation of tartar emetic, which is used in cough syrup as an expectorant. DL-Tartaric acid can be used:In the Debus–Radziszewski reaction as a weak acid for the synthesis of imidazolium ionic liquid. As an additive in electrochemical deposition technique for the synthesis of bismuth thin films to be used as X-ray absorbers.As a complexing agent for the synthesis of nano-crystalline indium tin oxide (ITO) powder.As a dopant for the synthesis of polyaniline nanofibers and nanotubes by oxidation polymerization.

Technology Process of d-Tartaric acid

There total 150 articles about d-Tartaric acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sorbic Acid (110-44-1,91751-55-2) → DL-tartaric acid (133-37-9,138508-61-9)

Guidance literature:

With potassium permanganate; at 0 ℃;

Reference yield:

hydrogen cyanide (74-90-8) + Glyoxal (131543-46-9,107-22-2) → DL-tartaric acid (133-37-9,138508-61-9)

Guidance literature:

With hydrogenchloride;

Reference yield:

mannitol (69-65-8) → DL-tartaric acid (133-37-9,138508-61-9)

Guidance literature:

With nitric acid;

upstream raw materials:

sorbic Acid

hydrogen cyanide

Glyoxal

mannitol

Downstream raw materials:

tartaric acid dipropyl ester

DL-tartaric acid monoethyl ester

(+/-)-diethyl tartrate

tartaric acid diisobutyl ester

Refernces

• 1、 Karimi Ahmadabad, Fatemeh,Pourayoubi, Mehrdad,Bakhshi, Hadi. "Decorated single-enantiomer phosphoramide-based silica/magnetic nanocomposites for direct enantioseparation". . p. 27147 - 27156. Retrieved 2019.
• 2、 Barch. "". . p. 3653,3656. Retrieved 1933.
• 3、 Church,Blumberg. "-". . p. 1780. Retrieved 1951.
• 4、 -. "Plaster retarding composition". Example 1. . Retrieved 2008/06/13.