Carbon monoxide;2,3,7,8,12,13,17,18-octaethylporphyrin-21,22-diide;ruthenium(2+)

Base Information

Chemical Name:Carbon monoxide;2,3,7,8,12,13,17,18-octaethylporphyrin-21,22-diide;ruthenium(2+)
CAS No.:41636-35-5
Molecular Formula:C37H44N4ORu
Molecular Weight:661.853
Hs Code.:
European Community (EC) Number:631-011-4
Mol file:41636-35-5.mol

Synonyms:41636-35-5;2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine ruthenium(II) carbonyl

Suppliers and Price of Carbon monoxide;2,3,7,8,12,13,17,18-octaethylporphyrin-21,22-diide;ruthenium(2+)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine ruthenium(II) carbonyl
100mg
$ 251.00

American Custom Chemicals Corporation
2,3,7,8,12,13,17,18-OCTAETHYL-21H,23H-PORPHINE RUTHENIUM(II) CARBONYL 95.00%
100MG
$ 751.91

Total 7 raw suppliers

Chemical Property of Carbon monoxide;2,3,7,8,12,13,17,18-octaethylporphyrin-21,22-diide;ruthenium(2+)

Chemical Property:

PSA：50.50000
LogP:5.61280
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:8
Exact Mass:662.255852
Heavy Atom Count:43
Complexity:613

Purity/Quality:

99% ^*data from raw suppliers

2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine ruthenium(II) carbonyl ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/21/22-36/37/38
Safety Statements: 26-36

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC1=C(C2=CC3=NC(=CC4=NC(=CC5=C(C(=C([N-]5)C=C1[N-]2)CC)CC)C(=C4CC)CC)C(=C3CC)CC)CC.[C-]#[O+].[Ru+2]
Uses 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine ruthenium(II) carbonyl (RuOEP )can form blended polymeric films with poly (3-hexythiopene-2,5-diyl)( P3HT).

Technology Process of Carbon monoxide;2,3,7,8,12,13,17,18-octaethylporphyrin-21,22-diide;ruthenium(2+)

There total 2 articles about Carbon monoxide;2,3,7,8,12,13,17,18-octaethylporphyrin-21,22-diide;ruthenium(2+) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 113469-04-8
bis(nitrosobenzene){2,37,8,12,13,17,18-octaethylporphyrinato^(2-)}ruthenium⁽²⁺⁾

: 41636-35-5
2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine ruthenium(II) carbonyl

: 586-96-9
Nitrosobenzene

Guidance literature:: With carbon monoxide; In dichloromethane; CH2Cl2 soln. of the Ru complex subjected to 1 atm CO; Ru(OEP)(PhNO)(CO) detected in situ at lower temps. (<-40°C);
DOI:10.1016/S0020-1693(00)86366-5

Reference yield:

: 7031-93-8
2,2,6,6-tetramethylpiperidin-1-ol

: {Ru(2,3,7,8,12,13,17,18-octaethylporphyrinate)(CH₃)}

: 41636-35-5
2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine ruthenium(II) carbonyl

Guidance literature:: In benzene; byproducts: Ru2(N4C20H4(C2H5)8)2; under inert atm., addn. of excess of piperidine to complex soln. at room temp., further unidentified product; monitored by 1H-NMR and UV-VIS;

Reference yield: 82.0%

: 41636-35-5
2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine ruthenium(II) carbonyl

: nitrosonium tetrafluoroborate

: 352-13-6
4-flourophenylmagnesium bromide

: (CHC₄N(C₂H₅)2CHC₄N(C₂H₅)2)2RuNOC₆H₄F*0.13CH₂Cl₂

Guidance literature:: In tetrahydrofuran; dichloromethane; byproducts: CO; under Ar or N2, standard Schlenk technique; NOBF4 added to a soln. of Rucomplex in CH2Cl2; stirred for 30 min; evapd.; THF added; Grignard reag ent in THF added; reaction was complete within 10 min (IR monitoring); evapd.; redissolved in CH2Cl2 and filtered; evapd. under inert atmosphere; elem. anal.; single crystal X-ray diffraction analysis;
DOI:10.1021/ja010276m