1,4-Diphenyl-1,4-diphosphatetralin

Base Information

Chemical Name:1,4-Diphenyl-1,4-diphosphatetralin
CAS No.:56700-81-3
Molecular Formula:C₂₀H₁₈P₂
Molecular Weight:320.31
Hs Code.:
Mol file:56700-81-3.mol

Synonyms:1,2,3,4-Tetrahydro-1,4-diphenyl-1,4-benzodiphosphorin;1,4-Diphenyl-1,4-diphosphatetralin

Suppliers and Price of 1,4-Diphenyl-1,4-diphosphatetralin

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 1,4-Diphenyl-1,4-diphosphatetralin

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 1,4-Diphenyl-1,4-diphosphatetralin

There total 1 articles about 1,4-Diphenyl-1,4-diphosphatetralin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 38023-29-9
1,2-diphenylphosphinobenzene

: 107-06-2,52399-93-6
1,2-dichloro-ethane

: 56700-81-3,38234-86-5
1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine

Guidance literature:: Multistep reaction; (i) nBuLi, hexane, THF, (ii) /BRN= 605264/;
DOI:10.1039/P19720002548

Reference yield: 95.0%

: 56700-81-3,38234-86-5
1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine

: [Pt(1,5-cyclooctadiene)(1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine)][BF₄]2

: [Pt(1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine)2][BF₄]2

Guidance literature:: In chloroform; byproducts: 1,5-cyclooctadiene; (N2); using Schlenk techniques; addn. of P(Ph)(CH2CH2)(C6H4)P(Ph) to stirred soln. of Pt(P(Ph)(CH2CH2)(C6H4)P(Ph)(COD)(BF4)2 in CHCl3 for 1.5 h; pptn., filtration, washing with Et2O; drying in vac.; elem. anal.;
DOI:10.1016/j.jorganchem.2007.08.003

Reference yield: 90.0%

: 56700-81-3,38234-86-5
1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine

: 14104-20-2
silver tetrafluoroborate

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: [Pd(1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine)2][BF₄]2

Guidance literature:: In nitromethane; dichloromethane; byproducts: AgCl; (N2); using Schlenk technqiues; addn. of soln. of 1,2,3,4-tetrahydro-1,4-diphenyl-1,4-benzodiphosphinine (bedip) in CH2Cl2 to stirred soln. of PdCl2(COD) in CH2Cl2 for 24 h; filtration, addn. of bedip in CH2Cl2 and AgBF4 in MeNO2; stirring for 24 h; filtration, drying in vac., elem. anal.;
DOI:10.1016/j.jorganchem.2007.08.003