Hexyl vinyl carbinol

Base Information

• Chemical Name: Hexyl vinyl carbinol
• CAS No.: 79605-61-1
• Molecular Formula: C₉H₁₈O
• Molecular Weight: 142.241
• Mol file: 79605-61-1.mol

Synonyms:

Chemical Property of Hexyl vinyl carbinol

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Hexyl vinyl carbinol

There total 73 articles about Hexyl vinyl carbinol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

heptanal (111-71-7) + vinyl magnesium bromide (1826-67-1) → non-1-en-3-ol (21964-44-3,79605-61-1)

Guidance literature:

In tetrahydrofuran; diethyl ether; at 0 - 20 ℃; Inert atmosphere;

DOI:10.15227/orgsyn.068.0210

Reference yield: 92.0%

1-Iodohexane (638-45-9) + acrolein (107-02-8,25068-14-8) → non-1-en-3-ol (21964-44-3,79605-61-1)

Guidance literature:

1-Iodohexane; With iodine; magnesium; In diethyl ether; for 0.333333h; Inert atmosphere; Reflux;

acrolein; In diethyl ether; at 0 - 20 ℃; for 1h; Inert atmosphere;

DOI:10.1002/anie.201700620

Reference yield: 89.0%

1-Nitro-2-[((Z)-non-2-enyl)selanyl]-benzene (398136-79-3) → non-1-en-3-ol (21964-44-3,79605-61-1)

Guidance literature:

1-Nitro-2-[((Z)-non-2-enyl)selanyl]-benzene; With Cumene hydroperoxide; 4 A molecular sieve; vanadyl acetylacetonate; In dichloromethane; at -10 ℃; for 0.5h;

With tributylphosphine; In dichloromethane; at -10 ℃; for 0.0833333h;

DOI:10.1039/b316502g

upstream raw materials:

n-hexylmagnesium bromide

acrolein

heptanal

chloroethylene

Downstream raw materials:

1,2R-epoxy-nonane-3S-ol

(R)-non-1-en-3-ol

(S)-1-[(S)-oxiran-2-yl]heptan-1-ol

(S)-1-nonen-3-ol

Refernces

• 1、 Hossein Javadi, Sayed,Zareyee, Daryoush,Monfared, Azam,Didehban, Khadijeh,Mirshokraee, Sayed Ahmmad. "Silica-coated Fe3O4 magnetic nanoparticles-supported sulfonic acid as a highly active and reusable catalyst in chemoselective deprotection of tert-butyldimethylsilyl (TBDMS) ethers". supporting information. p. 7 - 12. Retrieved 2019/11/03.
• 2、 Dethe, Dattatraya H.,Nagabhushana, C. B.. "Ruthenium-Catalyzed Direct Dehydrogenative Cross-Coupling of Allyl Alcohols and Acrylates: Application to Total Synthesis of Hydroxy β-Sanshool, ZP-Amide I, and Chondrillin". supporting information. . Retrieved 2020/02/15.