N-(2-Bromophenyl)benzamide

Base Information

• Chemical Name: N-(2-Bromophenyl)benzamide
• CAS No.: 70787-27-8
• Molecular Formula: C13H10BrNO
• Molecular Weight: 276.132
• NSC Number: 406273
• DSSTox Substance ID: DTXSID00221051
• Nikkaji Number: J1.008.176I
• Wikidata: Q83098640
• Mol file: 70787-27-8.mol

Synonyms:N-(2-Bromophenyl)benzamide;Benzamide, N-(2-bromophenyl)-;70787-27-8;Benzanilide, 2'-bromo-;BRN 2724791;0-12-00-00632 (Beilstein Handbook Reference);NSC406273;DTXSID00221051;STK325490;AKOS000168809;N-Benzoyl derivative of o-bromoaniline;NSC 406273;NSC-406273;LS-25896;EU-0069605;10.14272/USYBDUIHFMIQCP-UHFFFAOYSA-N;doi:10.14272/USYBDUIHFMIQCP-UHFFFAOYSA-N;SR-01000414624;SR-01000414624-1;Z27784784

Chemical Property of N-(2-Bromophenyl)benzamide

Chemical Property:

• Vapor Pressure: 0.002mmHg at 25°C
• Refractive Index: 1.665
• Boiling Point: 291°Cat760mmHg
• Flash Point: 129.8°C
• PSA: 29.10000
• Density: 1.496g/cm³
• LogP: 3.77440
• XLogP3: 3.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 274.99458
• Heavy Atom Count: 16
• Complexity: 238

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=O)NC2=CC=CC=C2Br

Technology Process of N-(2-Bromophenyl)benzamide

There total 29 articles about N-(2-Bromophenyl)benzamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

benzoyl chloride (98-88-4) + 2-bromoaniline (615-36-1) → N-(2-bromophenyl)benzamide (70787-27-8)

Guidance literature:

With 1,10-Phenanthroline; In acetonitrile; at 90 ℃; for 1h; Temperature; Inert atmosphere; Sealed tube;

DOI:10.1016/j.tetlet.2015.10.078

Reference yield: 98.0%

N-(2-bromophenyl)benzothioamide (85433-21-2) → N-(2-bromophenyl)benzamide (70787-27-8)

Guidance literature:

With dihydrogen peroxide; zirconium(IV) chloride; In ethanol; water; at 25 ℃; for 0.0333333h; chemoselective reaction;

DOI:10.1055/s-0028-1083314

Reference yield: 97.0%

iodobenzene (591-50-4) + carbon monoxide (201230-82-2) + 2-bromoaniline (615-36-1) → N-(2-bromophenyl)benzamide (70787-27-8)

Guidance literature:

iodobenzene; carbon monoxide; 2-bromoaniline; With palladium diacetate; triethylamine; In water; for 0.166667h;

With carbon monoxide; In water; at 100 ℃; for 8h; under 10343.2 Torr;

DOI:10.1080/00397911.2010.523155

upstream raw materials:

benzoyl chloride

2-bromoaniline

N-(2,4-dibromophenyl)benzamide

4-bromo-N-(2-bromophenyl)benzamide

Downstream raw materials:

N-(2-bromophenyl)benzothioamide

N-(2-Bromphenyl)benzimidoylchlorid

N-<2-(1-methylimidazol-2-yl)phenyl>benzamide

diphenylamine