methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate

Base Information

Chemical Name:methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate
CAS No.:514816-42-3
Molecular Formula:C6H7BrN2O2
Molecular Weight:219.038
Hs Code.:2933199090
European Community (EC) Number:836-336-7
DSSTox Substance ID:DTXSID50350087
Wikidata:Q82125843
Mol file:514816-42-3.mol

Synonyms:methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate;514816-42-3;methyl 4-bromo-2-methylpyrazole-3-carboxylate;MFCD01459850;1H-Pyrazole-5-carboxylic acid, 4-bromo-1-methyl-, methyl ester;SCHEMBL4813243;DTXSID50350087;XOGHZBXSBLBJHQ-UHFFFAOYSA-N;AMY12037;BBL013090;STK315996;AKOS003744475;CS-W000414;AC-30767;AS-39454;BB 0255204;FT-0679636;EN300-232375;Methyl 4-bromo-2-methyl-pyrazole-3-carboxylate;A871272;A1-24367;Methyl 4-bromo-2-methyl-2H-pyrazole-3-carboxylate;METHYL4-BROMO-1-METHYL-1H-PYRAZOLE-5-CARBOXYLATE;4-bromo-2-methyl-2H-pyrazol-3-carboxylic acid methyl ester;4-bromo-2-methyl-2h-pyrazole-3-carboxylic acid methyl ester

Suppliers and Price of methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
Methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate
100mg
$ 305.00

TRC
Methyl4-bromo-1-methyl-1H-pyrazole-5-carboxylate
500mg
$ 70.00

Matrix Scientific
Methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate
500mg
$ 62.00

Crysdot
Methyl4-bromo-1-methyl-1H-pyrazole-5-carboxylate 95+%
5g
$ 285.00

Crysdot
Methyl4-bromo-1-methyl-1H-pyrazole-5-carboxylate 95+%
1g
$ 95.00

Crysdot
Methyl4-bromo-1-methyl-1H-pyrazole-5-carboxylate 95+%
10g
$ 500.00

Chemenu
Methyl4-bromo-1-methyl-1H-pyrazole-5-carboxylate 95+%
10g
$ 480.00

Chemenu
Methyl4-bromo-1-methyl-1H-pyrazole-5-carboxylate 95+%
5g
$ 224.00

Chemenu
Methyl4-bromo-1-methyl-1H-pyrazole-5-carboxylate 95+%
1g
$ 55.00

ChemBridge Corporation
methyl4-bromo-1-methyl-1H-pyrazole-5-carboxylate 95%
1 g
$ 70.00

Total 21 raw suppliers

Chemical Property of methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate

Chemical Property:

Vapor Pressure:0.00477mmHg at 25°C
Boiling Point:276.5°C at 760 mmHg
PKA:-1.57±0.10(Predicted)
Flash Point:121°C
PSA：44.12000
Density:1.67g/cm³
LogP:0.96920
Storage Temp.:2-8°C
XLogP3:1.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:217.96909
Heavy Atom Count:11
Complexity:165

Purity/Quality:

97% ^*data from raw suppliers

Methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CN1C(=C(C=N1)Br)C(=O)OC

Technology Process of methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate

There total 2 articles about methyl 4-bromo-1-methyl-1H-pyrazole-5-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.4%

: 67-56-1
methanol

: 84547-84-2
4-bromo-2-methyl-2H-pyrazole-3-carboxylic acid

: 514816-42-3
4-bromo-2-methyl-2H-pyrazole-3-carboxylic acid methyl ester

Guidance literature:: With thionyl chloride; for 18h; Reflux;

Reference yield: 51.8%

: 81190-89-8,1639902-31-0,190263-20-8
methyl 4-bromo-1H-pyrazole-3-carboxylate

: 74-88-4
methyl iodide

: 514816-42-3
4-bromo-2-methyl-2H-pyrazole-3-carboxylic acid methyl ester

: 211738-66-8
4-bromo-1-methyl-1H-pyrazole-3-carboxylic acid methyl ester

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; at 0 - 25 ℃; for 16h; Inert atmosphere;

Reference yield: 89.8%

: 514816-42-3
4-bromo-2-methyl-2H-pyrazole-3-carboxylic acid methyl ester

: 98-80-6
phenylboronic acid

: 23097-85-0
methyl 2-methyl-4-phenyl-2H-pyrazole-3-carboxylate

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 12h; Inert atmosphere;