Methyl JasMonate (Mixture of isoMers)

Base Information

Chemical Name:Methyl JasMonate (Mixture of isoMers)
CAS No.:1101843-02-0
Molecular Formula:C13H20O3
Molecular Weight:224.3
Hs Code.:
Mol file:1101843-02-0.mol

Synonyms:3-methoxycarbonylmethyl-2-(cis-2''-pentenyl)-cyclopentanone;methyl-propenyl sulfide;methyl 2-(cis-pent-2-enyl)-3-oxo-cyclopentylacetate;methyl 3-oxo-2-[(2Z)-2-pentenyl]cyclopentaneacetate;

Suppliers and Price of Methyl JasMonate (Mixture of isoMers)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
MethylJasmonate(90%)
5g
$ 415.00

TCI Chemical
Methyl Jasmonate (mixture of isomers) >90.0%(GC)
25g
$ 396.00

TCI Chemical
Methyl Jasmonate (mixture of isomers) >90.0%(GC)
5g
$ 122.00

Total 6 raw suppliers

Chemical Property of Methyl JasMonate (Mixture of isoMers)

Chemical Property:

Refractive Index:1.47
Boiling Point:96°C/2.7mmHg(lit.)
Flash Point:156°C(lit.)
PSA：43.37000
Density:1.003±0.06 g/cm3(Predicted)
LogP:2.50110

Purity/Quality:

97% ^*data from raw suppliers

MethylJasmonate(90%) ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Methyl JasMonate (Mixture of isoMers)

There total 29 articles about Methyl JasMonate (Mixture of isoMers) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 67-56-1
methanol

: 221682-41-3
(Z)-2-(2-(but-2-en-1-yl)-3-oxocyclopentyl)acetic acid

: 1101843-02-0
methyl jasmonate

Guidance literature:: With sulfuric acid; at 40 ℃; for 3h;
DOI:10.1246/bcsj.54.505

Reference yield: 78.0%

: 55254-73-4
2-methoxycarbonyl-3-<(methoxycarbonyl)methyl>-2-<(Z)-2-pentenyl>cyclopentanone

: 1101843-02-0
methyl jasmonate

Guidance literature:: With water; sodium chloride; In dimethyl sulfoxide; at 180 ℃; for 4h;
DOI:10.1080/00397919208019310

Reference yield:

: 41653-95-6
(Z)-4-heptenoic acid

: 1101843-02-0
methyl jasmonate

Guidance literature:: Multi-step reaction with 7 steps

1: 74 percent / SOCl₂, pyridine / diethyl ether / 2 h / Ambient temperature

2: tetrahydrofuran / 2 h / -78 - 20 °C

3: 68 percent / oxalic acid / H₂O / 3 h / Heating

4: 69 percent / NaOH / H₂O; dioxane / 1.5 h / Heating

5: 92 percent / NaH / methanol / 3 h / -10 - -5 °C

6: 1.) 10percent aq. NaOH, 2.) 3percent aq. H₂SO₄ / 1.) overnight, 2.) reflux, 5 h

7: 92 percent / H₂SO₄ / 3 h / 40 °C

With pyridine; sodium hydroxide; thionyl chloride; sulfuric acid; oxalic acid; sodium hydride; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; water;
DOI:10.1246/bcsj.54.505