A-Methylbenzylzinc bromide

Base Information

Chemical Name:A-Methylbenzylzinc bromide
CAS No.:85459-20-7
Molecular Formula:C8H9BrZn
Molecular Weight:250.453
Hs Code.:2931900090
European Community (EC) Number:804-636-7
Mol file:85459-20-7.mol

Synonyms:85459-20-7;A-METHYLBENZYLZINC BROMIDE;a-Methylbenzylzinc bromide 0.5 M in Tetrahydrofuran;bromozinc(1+);ethylbenzene;alpha-methylbenzyl zinc bromide;MFCD01311436;AKOS016018002

Suppliers and Price of A-Methylbenzylzinc bromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
α-Methylbenzylzinc bromide solution 0.5 M in THF
50ml
$ 209.00

Rieke Metals
Alpha-Methylbenzylzincchloride
100mL
$ 966.00

Rieke Metals
Alpha-Methylbenzylzincchloride
50mL
$ 602.00

American Custom Chemicals Corporation
A-METHYLBENZYLZINC BROMIDE 95.00%
1L
$ 7969.50

American Custom Chemicals Corporation
A-METHYLBENZYLZINC BROMIDE 95.00%
500ML
$ 5313.00

American Custom Chemicals Corporation
A-METHYLBENZYLZINC BROMIDE 95.00%
100ML
$ 2760.45

Alfa Aesar
alpha-Methylbenzylzinc chloride, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
50ml
$ 140.00

Total 8 raw suppliers

Chemical Property of A-Methylbenzylzinc bromide

Chemical Property:

Flash Point:1 °F
PSA：0.00000
Density:0.965 g/mL at 25 °C
LogP:3.23550
Storage Temp.:2-8°C
Sensitive.:Air Sensitive
Water Solubility.:Reacts with water.
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:1
Exact Mass:247.91790
Heavy Atom Count:10
Complexity:60.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

α-Methylbenzylzinc bromide solution 0.5 M in THF ^*data from reagent suppliers

Safty Information:

Pictogram(s): F,Xn
Hazard Codes:F,Xn
Statements: 14-19-22-36/38-40-36/37-11
Safety Statements: 16-26-33-36-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[CH-]C1=CC=CC=C1.[Zn+]Br

Technology Process of A-Methylbenzylzinc bromide

There total 2 articles about A-Methylbenzylzinc bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 585-71-7,38661-81-3
(1-bromoethyl)benzne

: 106-93-4
ethylene dibromide

: 85459-20-7
(α-methylbenzyl)zinc bromide

Guidance literature:: With chloro-trimethyl-silane; zinc; In tetrahydrofuran; at 70 ℃; for 1h; Inert atmosphere;

Reference yield:

: 585-71-7,38661-81-3
(1-bromoethyl)benzne

: 85459-20-7
(α-methylbenzyl)zinc bromide

Guidance literature:: With chloro-trimethyl-silane; ethylene dibromide; lithium chloride; zinc; In tetrahydrofuran; at 20 - 50 ℃; Schlenk technique; Inert atmosphere;
DOI:10.1021/ol4032683

Reference yield: 95.0%

: 623-03-0
4-Cyanochlorobenzene

: 85459-20-7
(α-methylbenzyl)zinc bromide

: 125847-21-4
1-(4-cyanophenyl)-1-phenylethane

Guidance literature:: With dichloro(1,3-bis(2,6-bis(3-pentyl)phenyl)imidazolin-2-ylidene)(3-chloropyridyl)palladium(II); In tetrahydrofuran; toluene; at 0 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1039/c0cc04835f