TRANS-2-(1-CYCLOHEXENYL)VINYLBORONIC ACID PINACOL ESTER

Base Information

• Chemical Name: TRANS-2-(1-CYCLOHEXENYL)VINYLBORONIC ACID PINACOL ESTER
• CAS No.: 620634-96-0
• Molecular Formula: C14H25BO3
• Molecular Weight: 234.146
• Hs Code.: 2934999090
• Mol file: 620634-96-0.mol

Synonyms:TRANS-2-(1-CYCLOHEXENYL)VINYLBORONIC ACID PINACOL ESTER

Chemical Property of TRANS-2-(1-CYCLOHEXENYL)VINYLBORONIC ACID PINACOL ESTER

Chemical Property:

• Refractive Index: n20/D 1.505
• Flash Point: 110 °C
• PSA: 18.46000
• Density: 0.963 g/mL at 25 °C
• LogP: 3.67440

Purity/Quality:

99% ^*data from raw suppliers

trans-2-(1-Cyclohexenyl)vinylboronic acid pinacol ester 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRANS-2-(1-CYCLOHEXENYL)VINYLBORONIC ACID PINACOL ESTER

There total 5 articles about TRANS-2-(1-CYCLOHEXENYL)VINYLBORONIC ACID PINACOL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

methanol (67-56-1) + 1-ethenylcyclohexene (931-49-7) + bis(pinacol)diborane (73183-34-3) → C6H9CHCH(BO2(C(CH3)2)2) (620634-96-0) + 2-(1-(cyclohex-1-en-1-yl)vinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Guidance literature:

With catalyst: Cu(OtBu)/PPh₃; In tetrahydrofuran; methanol; to mixt. of bis(pinacolato)diboron, substrate, catalyst (THF) added MeOHat room temp.; reaction for 1.5-17 h;; (1)H NMR;

DOI:10.1002/anie.201007182

Reference yield:

1-ethenylcyclohexene (931-49-7) + bis(pinacol)diborane (73183-34-3) → C6H9CHCH(BO2(C(CH3)2)2) (620634-96-0)

Guidance literature:

With copper(II) ferrite; potassium tert-butylate; In methanol; at 50 ℃; for 12h; regioselective reaction; Green chemistry;

DOI:10.1016/j.apcata.2016.03.019

Reference yield:

1-ethenylcyclohexene (931-49-7) + 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane (25015-63-8) → C6H9CHCH(BO2(C(CH3)2)2) (620634-96-0)

Guidance literature:

With Schwartz's reagent; triethylamine; at 60 ℃; for 15h;

DOI:10.1021/ol2009297

upstream raw materials:

methanol

1-ethenylcyclohexene

bis(pinacol)diborane

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

Downstream raw materials:

(E)-tert-butyl((2-(cyclohex-1-en-1-yl)vinyl)oxy)dimethylsilane

1-phenyl-4,5,6,7-tetrahydro-1H-indole