Benzoyl 3-methylpyridinium-1-ylamine anion

Base Information

• Chemical Name: Benzoyl 3-methylpyridinium-1-ylamine anion
• CAS No.: 31382-86-2
• Molecular Formula: C13H12N2O
• Molecular Weight: 212.251
• Mol file: 31382-86-2.mol

Synonyms:1-Benzamido-3-picolinium hydroxide inner salt;3-Methyl-1-[(α-oxylatobenzylidene)amino]pyridinium;Benzoyl 3-methylpyridinium-1-ylamine anion;N-Benzoyl-3-methyl-1-azoniabenzene-1-amineanion

Chemical Property of Benzoyl 3-methylpyridinium-1-ylamine anion

Chemical Property:

• Melting Point: 142 °C
• PSA: 37.82000
• LogP: 2.94970

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzoyl 3-methylpyridinium-1-ylamine anion

There total 6 articles about Benzoyl 3-methylpyridinium-1-ylamine anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzoyl chloride (98-88-4) + (3-methylpyridin-1-ium-1-yl)amide (59046-22-9) → N-<(phenylcarbonyl)imino>-3-methylpyridinium inner salt (31382-86-2)

Guidance literature:

With sodium hydroxide; at 25 ℃; for 12h; Yield given;

DOI:10.1021/jm00384a018

Reference yield:

3-Methylpyridine (108-99-6) + benzoyl chloride (98-88-4) → N-<(phenylcarbonyl)imino>-3-methylpyridinium inner salt (31382-86-2)

Guidance literature:

3-Methylpyridine; With O-(2,4-dinitrophenyl)hydroxylamine; In tetrahydrofuran; water; at 40 ℃; for 16h; Sealed tube;

With sodium hydroxide; In tetrahydrofuran; water; at 20 ℃; for 0.0833333h; Sealed tube;

benzoyl chloride; In tetrahydrofuran; water; for 5h; Sealed tube;

DOI:10.1002/ejoc.201403479

Reference yield:

Benzoic acid N'-{(1E,3Z)-5-[(E)-2,4-dinitro-phenylimino]-2-methyl-penta-1,3-dienyl}-hydrazide → N-<(phenylcarbonyl)imino>-3-methylpyridinium inner salt (31382-86-2)

Guidance literature:

With water; In 1,4-dioxane; for 12h; Yield given; Heating;

DOI:10.1002/jps.2600810515

upstream raw materials:

benzoyl chloride

(3-methylpyridin-1-ium-1-yl)amide

1-(2,4-dinitrophenyl)-3-methylpyridinium chloride

benzoic acid hydrazide

Downstream raw materials:

2-cyclohexenyl-6-methylpyrazolo[1,5-a]pyridine

2-cyclohexenyl-4-methylpyrazolo[1,5-a]pyridine

5-methyl-2-phenyl-N-benzoyliminopyridinium ylide

C₁₉H₁₆N₂O