(Z)-benzylidene-oxido-tert-butyl-azanium

Base Information

• Chemical Name: (Z)-benzylidene-oxido-tert-butyl-azanium
• CAS No.: 68315-30-0
• Molecular Formula: C₁₁H₁₅NO
• Molecular Weight: 177.246
• Mol file: 68315-30-0.mol

Synonyms:(Z)-benzylidene-oxido-tert-butyl-azanium

Chemical Property of (Z)-benzylidene-oxido-tert-butyl-azanium

Chemical Property:

Purity/Quality:

99%min ^*data from raw suppliers

(Z)-BENZYLIDENE-OXIDO-TERT-BUTYL-AZANIUM 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Z)-benzylidene-oxido-tert-butyl-azanium

There total 44 articles about (Z)-benzylidene-oxido-tert-butyl-azanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

N-tert-butyl-α-cyanobenzylhydroxylamine trimethylsilyl ether (105488-71-9) → N-tert-butyl-α-phenylnitrone (3376-24-7,68315-30-0)

Guidance literature:

With silver fluoride; In acetonitrile; at 80 ℃;

DOI:10.1039/c39860000789

Reference yield: 99.0%

N-benzyl-N-(tert-butyl)hydroxylamine (68883-38-5) → N-tert-butyl-α-phenylnitrone (3376-24-7,68315-30-0)

Guidance literature:

N-benzyl-N-(tert-butyl)hydroxylamine; With polytetrafluoroethylene; dmap; oxygen; 3,6-dichloro-1,2,4,5-tetrazine; for 0.0166667h;

Irradiation;

DOI:10.1055/a-1691-0449

Reference yield: 97.0%

N-tertbutylhydroxylamine hydrochloride (57497-39-9) + benzaldehyde (100-52-7) → N-tert-butyl-α-phenylnitrone (3376-24-7,68315-30-0)

Guidance literature:

With pyrrolidine; In dichloromethane; at 20 ℃; for 0.25h;

DOI:10.1021/acscatal.5b01726

upstream raw materials:

2-tert-butyl-3-phenyloxaziridine

acetonitrile

N-tert-Butylhydroxylamine

benzaldehyde

Downstream raw materials:

α-Methoxybenzyl-tert-butyl-nitroxyl-Radikal

methanol adduct of α-phenyl-N-t-butylnitrone

benzoyl-tert-butylnitroxyl radical

C₁₅H₂₄NO₂

Refernces

• 1、 Allain, Clémence,Audebert, Pierre,Claraz, Aurélie,Le, Tuan,Lyu, Jiyuan,Masson, Géraldine. "S -Tetrazine: Robust and Green Photoorganocatalyst for Aerobic Oxidation of N,N-Disubstituted Hydroxylamines to Nitrones". supporting information. . Retrieved 2021/12/06.
• 2、 Park, Jin,Park, Sehoon,Jang, Gwang Seok,Kim, Ran Hui,Jung, Jaehoon,Woo, Sang Kook. "Weak base-promoted selective rearrangement of oxaziridines to amidesviavisible-light photoredox catalysis". supporting information. p. 9995 - 9998. Retrieved 2021/10/06.