1-Methoxy-3-(pentafluorosulfanyl)benzene

Base Information

• Chemical Name: 1-Methoxy-3-(pentafluorosulfanyl)benzene
• CAS No.: 1272542-23-0
• Molecular Formula: C7H7F5OS
• Molecular Weight: 234.19
• Hs Code.: 2930909899
• Mol file: 1272542-23-0.mol

Synonyms:1-Methoxy-3-(pentafluorosulfanyl)benzene

Chemical Property of 1-Methoxy-3-(pentafluorosulfanyl)benzene

Chemical Property:

• PSA: 34.53000
• LogP: 4.35260

Purity/Quality:

98.5% ^*data from raw suppliers

1-METHOXY-3-(PENTAFLUOROSULFANYL)BENZENE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Methoxy-3-(pentafluorosulfanyl)benzene

There total 1 articles about 1-Methoxy-3-(pentafluorosulfanyl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

3-nitrophenylsulfur pentafluoride (2613-26-5) + sodium methylate (124-41-4) → 1-methoxy-3-(pentafluorosulfanyl)benzene (1272542-23-0)

Guidance literature:

In N,N-dimethyl-formamide; at 23 ℃; Inert atmosphere;

DOI:10.1039/d1cc06140b

Reference yield: 98.0%

1-methoxy-3-(pentafluorosulfanyl)benzene (1272542-23-0) → 3-hydroxy(pentafluorosulfanyl)benzene (672-31-1)

Guidance literature:

With octanol; potassium tert-butylate; In N,N-dimethyl-formamide; at 110 ℃; for 1h; Inert atmosphere;

DOI:10.1021/ol2001478

Reference yield: 94.0%

potassium hydrogen bifluoride + 1-methoxy-3-(pentafluorosulfanyl)benzene (1272542-23-0) + bis(pinacol)diborane (73183-34-3) → potassium 3-methoxy-5-(pentafluorosulfanyl)phenyltrifluoroborate

Guidance literature:

1-methoxy-3-(pentafluorosulfanyl)benzene; bis(pinacol)diborane; With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4′-di-(tert-butyl)-2,2′-bipyridyl; In tetrahydrofuran; at 80 ℃; for 24h; Inert atmosphere;

potassium hydrogen bifluoride; With water; In tetrahydrofuran; at 20 ℃; for 5h;

DOI:10.1021/ol4025666

upstream raw materials:

3-nitrophenylsulfur pentafluoride

sodium methylate

Downstream raw materials:

3-hydroxy(pentafluorosulfanyl)benzene