Trifluoroacetic acid 3-methylphenyl ester

Base Information

• Chemical Name: Trifluoroacetic acid 3-methylphenyl ester
• CAS No.: 1736-09-0
• Molecular Formula: C9H7F3O2
• Molecular Weight: 204.149
• Hs Code.: 2915900090
• Mol file: 1736-09-0.mol

Synonyms:Trifluoroacetic acid 3-methylphenyl ester;Trifluoroacetic acid m-tolyl ester;Acetic acid, 2,2,2-trifluoro-, 3-Methylphenyl ester

Chemical Property of Trifluoroacetic acid 3-methylphenyl ester

Chemical Property:

• Vapor Pressure: 2mmHg at 25°C
• Boiling Point: 164.1°C at 760 mmHg
• Flash Point: 33.1°C
• PSA: 26.30000
• Density: 1.278g/cm³
• LogP: 2.46270

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Trifluoroacetic acid 3-methylphenyl ester

There total 4 articles about Trifluoroacetic acid 3-methylphenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-methylbenzenediazonium tetrafluoroborate (1422-76-0) + trifluoroacetic acid (76-05-1) → m-Fluorotoluene (352-70-5) + 3-methylphenyl trifluoroacetate (1736-09-0)

Guidance literature:

Heating;

DOI:10.1246/bcsj.75.789

Reference yield:

lead (IV) trifluoroacetate (16656-82-9) + toluene (108-88-3,15644-74-3,16713-13-6) → 3-methylphenyl trifluoroacetate (1736-09-0) + 4-methylphenyl trifluoroacetate (1813-29-2) + 2-(trifluoroacetoxy)toluene (1736-10-3) + 3-methylphenyllead(IV)trifluoroacetate + 4-methylphenyllead(IV)trifluoroacetate + 2-methylphenyllead(IV)trifluoroacetate

Guidance literature:

In trifluoroacetic acid; at 25 ℃; Product distribution; competitive reaction in presence of benzene;

DOI:10.1021/jo01311a019

Reference yield:

3-methyl-phenol (108-39-4) + trifluoroacetic anhydride (407-25-0) → 3-methylphenyl trifluoroacetate (1736-09-0)

Guidance literature:

DOI:10.1021/ja01518a014

upstream raw materials:

3-methyl-phenol

trifluoroacetic anhydride

lead (IV) trifluoroacetate

toluene

Downstream raw materials:

1-methyl-3-trifluoromethyl-benzene

m-methyl-α,α,α-trifluoromethoxybenzene

3-pentafluoroethoxy-toluene

3-pentafluoroethyloxy-benzoic acid