Hydroxide

Base Information

• Chemical Name: Hydroxide
• CAS No.: 14280-30-9
• Deprecated CAS: 58390-08-2,58721-68-9
• Molecular Formula: HO
• Molecular Weight: 17.0073
• UNII: 9159UV381P
• DSSTox Substance ID: DTXSID8074281
• Nikkaji Number: J209.359F
• Wikipedia: Hydroxide ion
• Wikidata: Q199877,Q27109967
• RXCUI: 1314279
• Mol file: 14280-30-9.mol

Synonyms:hydroxide;hydroxide ion;hydroxyl ion;OH-

Chemical Property of Hydroxide

Chemical Property:

• Vapor Pressure: 24.5mmHg at 25°C
• Boiling Point: 100°Cat760mmHg
• Flash Point: °C
• PSA: 23.06000
• Density: g/cm³
• LogP: -0.17680
• XLogP3: -0.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 17.002739651
• Heavy Atom Count: 1
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [OH-]
• Uses: Hydroxide ions are released by the resin as anions are adsorbed from the liquid phase. The effect is elimination of acidity in the liquid and conversion of the resin to a salt form. Typically, the resin is restored to the OH? form with a 4% solution of NaOH. The hydroxide form is also used in salt splitting applications. resin ? N(CH3)3OH-+Na+ + Cl- ? resin ? N(CH3)3Cl- + Na+ + OH- Salt forms of a strong base anion exchangerare used to remove other anions for which the resin has greater selectivity. 2 resin ? N(CH3)3Cl- +2Na+SO42- ? (resin ? N(CH3)3)2SO42- +2 Na+ +2Cl-

Technology Process of Hydroxide

There total 1 articles about Hydroxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(C6H5)4(C4H2N)4(4C)Co(CO2)(2-) + water (7732-18-5) → cobalt(II) 5,10,15,20-tetraphenylporphyrin (14172-90-8) + carbon monoxide (201230-82-2) + hydroxide (14337-01-0,58721-68-9,14280-30-9)

Guidance literature:

In water;

DOI:10.1021/jp9807017

Reference yield:

C22H18Br2FeN2O10 + hydroxide (14337-01-0,58721-68-9,14280-30-9) → ferric hydroxide + C11H10BrNO5

Guidance literature:

With sodium chloride; In water; Reagent/catalyst; Concentration; Kinetics; Mechanism;

DOI:10.1134/S1070363215010296

Reference yield:

C28H24Br2FeN4O6 + hydroxide (14337-01-0,58721-68-9,14280-30-9) → ferric hydroxide + C14H13BrN2O3

Guidance literature:

With sodium chloride; In water; Reagent/catalyst; Concentration; Kinetics; Mechanism;

DOI:10.1134/S1070363215010296

upstream raw materials:

water

Downstream raw materials:

brilliant green

(4-Amino-3-methyl-phenyl)-bis-(4-amino-phenyl)-methanol

Refernces

Alkenenitrile transmissive olefination: Synthesis of the putative lignan "morinol I"

10.1002/ejoc.201101235

The research focuses on the development of a novel and efficient method for synthesizing Z-alkenenitriles, which are valuable synthetic intermediates and pharmacophores found in many bioactive natural products. The study aims to harness the power of six-electron reactions to drive the formal displacement of hydroxide from hydroxyalkenenitriles, a process that is typically challenging due to the poor leaving group nature of hydroxide. The researchers successfully developed a transmissive olefination strategy that utilizes readily available components: an aldehyde, acrylonitrile, and a Grignard reagent.

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