2-ethyloxolane

Base Information

• Chemical Name: 2-ethyloxolane
• CAS No.: 123931-62-4
• Molecular Formula: C₆H₁₂O
• Molecular Weight: 100.161
• Mol file: 123931-62-4.mol

Synonyms:2-ethyloxolane

Chemical Property of 2-ethyloxolane

Chemical Property:

• Vapor Pressure: 29.6mmHg at 25°C
• Boiling Point: 109°C at 760 mmHg
• Flash Point: 14°C
• Density: 0.853g/cm³

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-ethyloxolane

There total 56 articles about 2-ethyloxolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(S)-(+)-2-<2-O-(p-Tolylsulfonyl)ethyl>tetrahydrofuran (149706-97-8) → (R)-(-)-2-Ethyltetrahydrofuran (51769-31-4,123931-62-4)

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 0 ℃;

DOI:10.1021/jo00106a030

Reference yield: 82.0%

(S)-(+)-6-chlorohexan-3-ol (102108-31-6) → (S)-(+)-2-ethyltetrahydrofuran (102108-34-9,123931-62-4)

Guidance literature:

With sodium hydride; for 3h; Ambient temperature;

DOI:10.1021/ja00272a051

Reference yield: 76.0%

n-hexyl-hypochlorite (82004-64-6) → 2-ethyltetrahydrofuran (1003-30-1,123931-62-4) + 4-chloro-1-hexanol (58705-86-5) + hexanal (66-25-1) + hexan-1-ol (111-27-3)

Guidance literature:

With sodium hydrogencarbonate; iron(II) sulfate; In tetrachloromethane; Ambient temperature; protected from the light;

DOI:10.1016/0040-4020(81)85021-1

upstream raw materials:

3-(tetrahydrofuran-2-yl)propan-1-ol

(furan-2-yl)ethylene

2-ethylfuran

hexane-1,4-diol

Downstream raw materials:

1,4-diboromohexane

(+/-)-3c-ethyl-cyclohexene-⁽⁴⁾-dicarboxylic acid-(1r.2c)

1,5-dibromohexane

Refernces

• 1、 Ye, Tian-Nan,Li, Jiang,Kitano, Masaaki,Hosono, Hideo. "Unique nanocages of 12CaO·7Al2O3 boost heterolytic hydrogen activation and selective hydrogenation of heteroarenes over ruthenium catalyst". . p. 749 - 756. Retrieved 2017/05/22.
• 2、 Gartia, Yashraj,Ramidi, Punnamchandar,Jones, Darin E.,Pulla, Sharon,Ghosh, Anindya. "Nickel complex catalyzed efficient activation of sp3and sp 2c-h bonds for alkylation and arylation of oxygen containing heterocyclic molecules". . p. 507 - 515. Retrieved 2014/06/24.