Bis(2-methylallyl) carbonate

Base Information

Chemical Name:Bis(2-methylallyl) carbonate
CAS No.:64057-79-0
Deprecated CAS:252331-08-1
Molecular Formula:C9H14 O3
Molecular Weight:170.208
Hs Code.:2920909090
European Community (EC) Number:264-645-1
DSSTox Substance ID:DTXSID30948082
Nikkaji Number:J68.702B
Wikidata:Q82925875
Mol file:64057-79-0.mol

Synonyms:Dimethallyl carbonate;Bis(2-methylallyl) carbonate;64057-79-0;bis(2-methylprop-2-enyl) carbonate;Bis(methallyl) carbonate;Bis(2-Methyl-2-propenyl) carbonate;2-Propen-1-ol, 2-methyl-, carbonate (2:1);EINECS 264-645-1;BRN 1769142;2-Methyl-2-propen-1-ol carbonate (2:1);CARBONIC ACID, BIS(2-METHYLALLYL) ESTER;2-Propen-1-ol, 2-methyl-, 1,1'-carbonate;4-03-00-00011 (Beilstein Handbook Reference);2-methyl allyl carbonate;bis(2-methylallyl)carbonate;SCHEMBL1976400;DTXSID30948082;2-Bromo-6-fluorophenylboronicacid;Bis(2-methylallyl) carbonate, 97%;MFCD00008598;bis(2-methylprop-2-en-1-yl) carbonate;LS-51923;CS-0454494;FT-0693097;CARBONIC ACID BIS(2-METHYLALLYL) ESTER

Suppliers and Price of Bis(2-methylallyl) carbonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Alfa Aesar
Dimethallyl carbonate, 97%
25g
$ 128.00

Alfa Aesar
Dimethallyl carbonate, 97%
5g
$ 33.30

Total 12 raw suppliers

Chemical Property of Bis(2-methylallyl) carbonate

Chemical Property:

Vapor Pressure:0.323mmHg at 25°C
Melting Point:201.3°C
Refractive Index:1.4371
Boiling Point:199-202°C
Flash Point:199-202°C
PSA：35.53000
Density:0.963g/cm³
LogP:2.29180
XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:6
Exact Mass:170.094294304
Heavy Atom Count:12
Complexity:174

Purity/Quality:

98%Min ^*data from raw suppliers

Dimethallyl carbonate, 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 10
Safety Statements: 16

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=C)COC(=O)OCC(=C)C
Uses It is used as an intermediate in enantioselective tsuji enol silane allylation reaction.

Technology Process of Bis(2-methylallyl) carbonate

There total 5 articles about Bis(2-methylallyl) carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 124-38-9,18923-20-1
carbon dioxide

: 513-42-8
3-hydroxy-2-methyl-1-propene

: 64057-79-0
bis(2-methylallyl) carbonate

Guidance literature:: carbon dioxide; 3-hydroxy-2-methyl-1-propene; With dichloromethane; caesium carbonate; In 1-methyl-pyrrolidin-2-one; at 100 ℃; for 24h; under 760.051 Torr;

With sodium sulfate; In 1-methyl-pyrrolidin-2-one; dichloromethane; at 125 ℃; for 6h; Inert atmosphere;
DOI:10.1016/j.tet.2010.10.051

Reference yield: 61.0%

: 75-09-2
dichloromethane

: 124-38-9,18923-20-1
carbon dioxide

: 513-42-8
3-hydroxy-2-methyl-1-propene

: 64057-79-0
bis(2-methylallyl) carbonate

: 1262208-09-2
2-methylallyl (2-methylallyloxy)methyl carbonate

Guidance literature:: With caesium carbonate; In 1-methyl-pyrrolidin-2-one; at 100 ℃; for 24h; under 760.051 Torr;
DOI:10.1016/j.tet.2010.10.051