2-[(Butylimino)methyl]pyridine

Base Information

• Chemical Name: 2-[(Butylimino)methyl]pyridine
• CAS No.: 7032-24-8
• Molecular Formula: C10H14N2
• Molecular Weight: 162.235
• Mol file: 7032-24-8.mol

Synonyms:2-[(Butylimino)methyl]pyridine;N-(2-Pyridinylmethylene)-1-butanamine;N-Butyl(2-pyridyl)methanimine;N-Butyl-2-pyridinemethanimine;N-Butyl-2-pyridinylmethanimine;N-Butyl-2-pyridylmethanimine;Butyl ATRP ligand

Chemical Property of 2-[(Butylimino)methyl]pyridine

Chemical Property:

• Refractive Index: n20/D1.519
• Flash Point: 109℃
• PSA: 25.25000
• Density: 0.949 g/mL at 25 °C
• LogP: 2.30060

Purity/Quality:

95% ^*data from raw suppliers

N-Butyl-2-pyridylmethanimine 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-[(Butylimino)methyl]pyridine

There total 3 articles about 2-[(Butylimino)methyl]pyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

pyridine-2-carbaldehyde (1121-60-4) + N-butylamine (109-73-9,85404-21-3) → N-(pyridin-2-ylmethylene)butan-1-amine (7032-24-8)

Guidance literature:

pyridine-2-carbaldehyde; N-butylamine; In diethyl ether; at 30 ℃; for 0.166667h;

With magnesium(II) sulfate; In diethyl ether; at 30 ℃; for 1h;

DOI:10.1021/ma0359032

Reference yield: 89.0%

2-Hydroxymethylpyridine (586-98-1) + N-butylamine (109-73-9,85404-21-3) → N-(pyridin-2-ylmethylene)butan-1-amine (7032-24-8)

Guidance literature:

With [2,2]bipyridinyl; copper(l) iodide; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; In acetonitrile; at 25 - 30 ℃; for 12h;

DOI:10.1002/adsc.201200574

Reference yield:

→ N-(pyridin-2-ylmethylene)butan-1-amine (7032-24-8)

Guidance literature:

2-Pyridin-aldehyd, Butylamin, in Bzl., Erwaermen;

DOI:10.1246/bcsj.36.1150

upstream raw materials:

pyridine-2-carbaldehyde

N-butylamine

2-Hydroxymethylpyridine

Downstream raw materials:

2-(4-butyl-3-phenyl-4,5-dihydro-[1,2,4]oxadiazol-5-yl)-pyridine

N-((pyridin-2-yl)methyl)butan-1-amine

[(butylamino)(pyridin-2-yl)methyl]phenylphosphinic acid

1-(N-butylamino)-1-(2-pyridyl)methyldiphenylphosphine oxide

Refernces

• 1、 Shinkai et al.. "-". . p. 2600,2602. Retrieved 1979.
• 2、 Campbell, Joanna L. P.,Davies, Christopher D.,Ho?ek, Jan,Ko?ovsky, Pavel,Kysilka, Ond?ej,Popov, Kirill K.,Pour, Milan. "Reductive Amination Revisited: Reduction of Aldimines with Trichlorosilane Catalyzed by Dimethylformamide─Functional Group Tolerance, Scope, and Limitations". . p. 920 - 943. Retrieved 2022/01/27.
• 3、 Martínez-Martínez, Daniel,Santiago, M. León,Toscano, Rubén A.,Amézquita-Valencia, Manuel. "Molybdenum (VI) Complexes Containing Pyridylimine Ligands: Effect of the Imine Nitrogen Substituent in the Epoxidation Reaction". supporting information. p. 243 - 251. Retrieved 2020/12/30.