cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate

Base Information

Chemical Name:cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate
CAS No.:152227-36-6
Molecular Formula:
Molecular Weight:484.34384
Hs Code.:
European Community (EC) Number:805-738-4,823-614-8
Mol file:152227-36-6.mol

Synonyms:15746-57-3;cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate;152227-36-6;dichlororuthenium;2-pyridin-2-ylpyridine;dihydrate;609844-11-3;cis-Dichlorobis(2,2'-bipyridine)ruthenium (II) dihydrate;Dichlorobis(2,2'-bipyridine)ruthenium(II)dihydrate;Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate;cis-bis-(2,2'-bipyridine)dichlororuthenium(ii) dihydrate;CIS-DICHLOROBIS(2,2/'-BIPYRIDINE)RUTHENIUM (II) DIHYDRATE, 99;MFCD00015504;AKOS024258163;D84819;F20805;10.14272/NHKTUSUPCAKVHT-UHFFFAOYSA-L.1;doi:10.14272/NHKTUSUPCAKVHT-UHFFFAOYSA-L.1;cis-dichlorobis(2,2'-bipyridine)ruthenium(ii)dihydrate;BIS(2,2'-BIPYRIDINE) DICHLORORUTHENIUM DIHYDRATE;cis-Bis(2,2'-bipyridine)dichlororuthenium(II) dihydrate;cis-Dichlorobis(2,2'-bipyridine) ruthenium(II) dihydrate;cis-Dichlorobis-(2,2'-bipyridine)ruthenium-(ii)2-hydrate;Ruthenium, bis(2,2'-bipyridine-kappaN1,kappaN1')dichloro-

Suppliers and Price of cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 5 raw suppliers

Chemical Property of cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate

Chemical Property:

Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:2
Exact Mass:520.000672
Heavy Atom Count:29
Complexity:123

Purity/Quality:: 98%,99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.O.O.Cl[Ru]Cl

Technology Process of cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate

There total 5 articles about cis-Dichlorobis(2,2'-bipyridine)ruthenium(II) dihydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 366-18-7
[2,2]bipyridinyl

: 7732-18-5
water

: 10049-08-8,63767-78-2
ruthenium(III)chloride

: 152227-36-6,609844-11-3
dichlorobis(2,2'-bipyridine)ruthenium(II) tetrahydrate

Guidance literature:: With NaCl; sucrose; L-ascorbic acid; In H₂O; other Radiation; to water added NaCl, sucrose, L-ascorbic acid, 2,2'-bipyridine, RuCl3 and conc. HCl; mixt. refluxed under microwave irradiation for 5 min; aftercooling to room temp. compd. pptd.; ppt. collected by filtration under vac. to dryness; elem. anal.;
DOI:10.1016/j.ica.2009.07.028

Reference yield: 38.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 53729-70-7,75598-28-6,14911-99-0
{ruthenium(2,2'-bipyridine)(carbonyl)2Cl₂}

: 7697-37-2,78989-43-2
nitric acid

: 152227-36-6,609844-11-3
Ru(2,2'-bipyridine)2Cl2 * 3.5 H2O

: 163045-33-8
[Ru₂(2,2'-bipyridine)2Cl₅N(H₂O)]

Guidance literature:: In hydrogenchloride; nitric acid; aq. HNO3; heating Ru-complex with 37% HCl and 65% HNO3 (pressure vessel, 240°C, 12 h), slow cooling to room temp. (crystn.); filtration, washing (H2O), drying in air; elem. anal.;
DOI:10.1021/ic00115a021

Reference yield:

: [Ru(2,2'-bipyridine)2]CO₃

: 34795-02-3,152227-36-6,609844-11-3
trans-Ru(2,2'-bipyridine)2Cl2

Guidance literature:: With hydrogenchloride; In water; Irradiation (UV/VIS); Ru compound in 0.6 M HCl was irradiated for 2 h at 25°C under argon; filtrated, washed with water, 2-propanol and ethyl ether, air dried, suspended in CH3CN, filtrated, washed like before, elem. anal.;
DOI:10.1021/ic00131a060