CINNAMYLIDENE-TERT-BUTYLIMINE

Base Information

• Chemical Name: CINNAMYLIDENE-TERT-BUTYLIMINE
• CAS No.: 29940-86-1
• Molecular Formula: C13H17N
• Molecular Weight: 187.285
• Mol file: 29940-86-1.mol

Synonyms:CINNAMYLIDENE-TERT-BUTYLIMINE

Chemical Property of CINNAMYLIDENE-TERT-BUTYLIMINE

Chemical Property:

• PSA: 12.36000
• LogP: 3.56910

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CINNAMYLIDENE-TERT-BUTYLIMINE

There total 4 articles about CINNAMYLIDENE-TERT-BUTYLIMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

tert-butylamine (75-64-9) + 3-phenyl-propenal (104-55-2) → N-(tert-butyl)-3-phenylprop-2-en-1-imine (29940-86-1)

Guidance literature:

With magnesium sulfate; In benzene; for 0.5h; Ambient temperature;

DOI:10.1248/cpb.31.538

Reference yield:

(E)-3-phenylpropenal (14371-10-9) + tert-butylamine (75-64-9) → N-(tert-butyl)-3-phenylprop-2-en-1-imine (29940-86-1)

Guidance literature:

With magnesium sulfate; In benzene; at 20 ℃;

DOI:10.1039/c6ob01526c

Reference yield:

benzaldehyde (100-52-7) → N-(tert-butyl)-3-phenylprop-2-en-1-imine (29940-86-1)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene / 17 h / 85 °C

2: magnesium sulfate / dichloromethane / 20 °C

With magnesium sulfate; In dichloromethane; toluene; 1: |Wittig Olefination;

DOI:10.1002/chem.201800958

upstream raw materials:

tert-butylamine

3-phenyl-propenal

(E)-3-phenylpropenal

benzaldehyde

Downstream raw materials:

tert-Butyl-[1-((E)-styryl)-but-3-enyl]-amine

1-tert-Butyl-4-((E)-styryl)-azetidin-2-one

N-(tert-butyl)-3-phenylprop-2-en-1-amine

Refernces

• 1、 Jang, Gwang Seok,Lee, Junggeun,Seo, Jungseok,Woo, Sang Kook. "Synthesis of 4-Isoxazolines via Visible-Light Photoredox-Catalyzed [3 + 2] Cycloaddition of Oxaziridines with Alkynes". supporting information. p. 6448 - 6451. Retrieved 2017/12/08.
• 2、 Devi, Purabi,Sandhu, Jagir S.. "The Reaction of α,β-Unsaturated Aldimines with Benzofuroxan". . p. 427 - 428. Retrieved 2007/10/02.