2,3-Bis(nitrooxy)succinic acid

Base Information

• Chemical Name: 2,3-Bis(nitrooxy)succinic acid
• CAS No.: 610-20-8
• Molecular Formula: C4H4 N2 O10
• Molecular Weight: 240.083
• Hs Code.: 2918990090
• European Community (EC) Number: 210-211-1
• DSSTox Substance ID: DTXSID70883342
• Mol file: 610-20-8.mol

Synonyms:2,3-Bis(nitrooxy)succinic acid;610-20-8;2,3-dinitrooxybutanedioic acid;Butanedioic acid, 2,3-bis(nitrooxy)-;EINECS 210-211-1;2,3-dinitrooxy-butanedioic acid;2,3-dinitroxybutanedioic acid;SCHEMBL9222307;C4H4N2O10;DTXSID70883342;C4-H4-N2-O10;FT-0652346;A833006

Chemical Property of 2,3-Bis(nitrooxy)succinic acid

Chemical Property:

• Vapor Pressure: 7.72E-06mmHg at 25°C
• Boiling Point: 350.1°C at 760 mmHg
• Flash Point: 165.6°C
• PSA: 184.70000
• Density: 1.954g/cm³
• LogP: -0.64420
• XLogP3: 0
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 10
• Rotatable Bond Count: 5
• Exact Mass: 239.98659433
• Heavy Atom Count: 16
• Complexity: 282

Purity/Quality:

97% ^*data from raw suppliers

2,3-DINITROOXY-BUTANEDIOIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C(C(=O)O)O[N+](=O)[O-])(C(=O)O)O[N+](=O)[O-]

Technology Process of 2,3-Bis(nitrooxy)succinic acid

There total 2 articles about 2,3-Bis(nitrooxy)succinic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

tartaric acid (87-69-4,138508-61-9) → di-O-nitro-tartaric acid (610-20-8)

Guidance literature:

With sulfuric acid; nitric acid; at 20 ℃; for 2h;

DOI:10.1080/00304940609356002

Reference yield:

DL-tartaric acid (133-37-9,138508-61-9) → di-O-nitro-tartaric acid (610-20-8)

Guidance literature:

With sulfuric acid; nitric acid;

Reference yield: 62.0%

di-O-nitro-tartaric acid (610-20-8) + acetaldehyde (75-07-0,9002-91-9) → 2-Methylimidazole-4,5-dicarboxylic acid (5313-35-9)

Guidance literature:

With ammonium hydroxide; for 16h; -5 to - 100 deg C up to room temperature;

DOI:10.1021/jm00121a023

upstream raw materials:

DL-tartaric acid

tartaric acid

Downstream raw materials:

2-phenyl-1H-imidazole-4,5-dicarboxylic acid

2-Methylimidazole-4,5-dicarboxylic acid

DL-tartaric acid

2-propyl-1H-imidazole-4,5-dicarboxylic acid

Refernces

• 1、 Meth-Cohn, Otto,Williams, Nicola J. R.,MacKinnon, Angus,Howard, Judith A. K.. "The photochemistry of α-azidocinnamates - A reinvestigation". . p. 9837 - 9848. Retrieved 2007/10/03.