borane/ piperidine complex

Base Information

• Chemical Name: borane/ piperidine complex
• CAS No.: 4856-94-4
• Molecular Formula: C5H15BN
• Molecular Weight: 98.9839
• Mol file: 4856-94-4.mol

Synonyms:borane/ piperidine complex

Chemical Property of borane/ piperidine complex

Chemical Property:

• Melting Point: 81 - 83 °C
• PSA: 26.02000
• LogP: 0.11900

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of borane/ piperidine complex

There total 12 articles about borane/ piperidine complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

piperidine (110-89-4) + sodium tetrahydroborate (16940-66-2) → pyrrolidineboraneYpiperidineborane (4856-94-4)

Guidance literature:

With water; sodium hydrogencarbonate; In tetrahydrofuran; at 20 ℃; for 8h;

DOI:10.1039/c6cc06031e

Reference yield: 99.0%

→ pyrrolidineboraneYpiperidineborane (4856-94-4)

Guidance literature:

With Sodium hydrogenocarbonate; In water monomer;

Reference yield: 96.0%

piperidine (110-89-4) + borane-ammonia complex (10043-11-5) → pyrrolidineboraneYpiperidineborane (4856-94-4)

Guidance literature:

In tetrahydrofuran; for 1h; Reflux;

DOI:10.1039/c4ra03397c

upstream raw materials:

piperidine

diborane

piperazine

dimethyl sulfide borane

Downstream raw materials:

1-phenoxyboranyl-piperidine

hydrogen

N-(4-methylbenzoyl)piperidine

N-benzoylpiperidine

Refernces

• 1、 -. "AMINE-BORANES AS BIFUNCTIONAL REAGENTS FOR DIRECT AMIDATION OF CARBOXYLIC ACIDS". Paragraph 0007; 0063. . Retrieved 2022/03/04.
• 2、 Chen, Xuenian,Kang, Jia-Xin,Ma, Yan-Na,Miao, Yu-Qi. "Visible light-mediated synthesis of amides from carboxylic acids and amine-boranes". supporting information. p. 3595 - 3599. Retrieved 2021/06/06.