(3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-[(Z)-but-2-enyl]-2-chloro-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole

Base Information

Chemical Name:(3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-[(Z)-but-2-enyl]-2-chloro-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole
CAS No.:804559-38-4
Molecular Formula:C24H29Br2ClN2Si
Molecular Weight:568.85
Hs Code.:
European Community (EC) Number:663-641-0
Nikkaji Number:J2.111.589D
Mol file:804559-38-4.mol

Synonyms:804559-38-4;(3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-[(Z)-but-2-enyl]-2-chloro-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole;(3aR,7aR)-1,3-Bis(4-bromobenzyl)-2-((Z)-but-2-en-1-yl)-2-chlorooctahydro-1H-benzo[d][1,3,2]diazasilole;AKOS024462614;(R,R)-1,3-Bis-(4-bromobenzyl)-2-chlorooctahydro-2-(2Z)-crotyl-1H-1,3,2-benzodiazasilole, 97%

Suppliers and Price of (3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-[(Z)-but-2-enyl]-2-chloro-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(R,R)-1,3-BIS-(4-BROMOBENZYL)-2-CHLOROOCTAHYDRO-2-(Z)-CROTYL-2-1H-1,3,2-BENZODIAZASILOLE 97.00%
5MG
$ 498.58

Total 2 raw suppliers

Chemical Property of (3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-[(Z)-but-2-enyl]-2-chloro-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole

Chemical Property:

PSA：6.48000
LogP:7.47020
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:568.01348
Heavy Atom Count:30
Complexity:536

Purity/Quality:

99% ^*data from raw suppliers

(R,R)-1,3-BIS-(4-BROMOBENZYL)-2-CHLOROOCTAHYDRO-2-(Z)-CROTYL-2-1H-1,3,2-BENZODIAZASILOLE 97.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC=CC[Si]1(N(C2CCCCC2N1CC3=CC=C(C=C3)Br)CC4=CC=C(C=C4)Br)Cl
Isomeric SMILES:C/C=C\C[Si]1(N([C@@H]2CCCC[C@H]2N1CC3=CC=C(C=C3)Br)CC4=CC=C(C=C4)Br)Cl

Technology Process of (3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-[(Z)-but-2-enyl]-2-chloro-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole

There total 1 articles about (3aR,7aR)-1,3-bis[(4-bromophenyl)methyl]-2-[(Z)-but-2-enyl]-2-chloro-3a,4,5,6,7,7a-hexahydrobenzo[d][1,3,2]diazasilole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 18147-55-2,52885-13-9,49749-84-0
(Z)-crotyltrichlorosilane

: 546084-44-0
(1R,2R)-N,N'-di(4'-bromobenzyl)-1,2-diaminocyclohexane

: 804559-38-4
(R,R)-crotylsilane

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/ol0480731

Reference yield: 83.0%

: 104-53-0
3-phenyl-propionaldehyde

: 804559-38-4
(R,R)-crotylsilane

: 129170-74-7
(3R,4R)-4-methyl-1-phenylhex-5-en-3-ol?

Guidance literature:: With scandium tris(trifluoromethanesulfonate); In dichloromethane; at 0 ℃; for 3h; Inert atmosphere;
DOI:10.1021/ol3033237