but-2-enyltrichlorosilane

Base Information

• Chemical Name: but-2-enyltrichlorosilane
• CAS No.: 18147-55-2
• Molecular Formula: C₄H₇Cl₃Si
• Molecular Weight: 189.544
• Mol file: 18147-55-2.mol

Synonyms:but-2-enyltrichlorosilane

Chemical Property of but-2-enyltrichlorosilane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of but-2-enyltrichlorosilane

There total 3 articles about but-2-enyltrichlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.4%

3-Chloro-2-methylpropene (563-47-3) → trichloro(2-methyl-2-propenyl)silane (18147-56-3) + 1,1,1,3,3,3-hexachloro-1,3-disilapropane (4142-85-2) + (Z)-crotyltrichlorosilane (18147-55-2,52885-13-9,49749-84-0) + Phenyltrichlorosilane (98-13-5) + 1,1,1,5,5,5-hexachloro-3-methyl-1,5-disila-1-pentene

Guidance literature:

With hexachlorodisilane; at 520 ℃; for 30h; Product distribution; Mechanism;

Reference yield: 8.6%

3-Chloro-2-methylpropene (563-47-3) → trichloro(2-methyl-2-propenyl)silane (18147-56-3) + (Z)-crotyltrichlorosilane (18147-55-2,52885-13-9,49749-84-0) + Phenyltrichlorosilane (98-13-5) + 1,1,1,5,5,5-hexachloro-3-methyl-1,5-disila-1-pentene

Guidance literature:

With hexachlorodisilane; at 520 ℃; for 0.00833333h; Further byproducts given;

Reference yield: 6.5%

trichlorosilane (10025-78-2) + buta-1,3-diene (106-99-0,130983-70-9,29406-96-0,9003-17-2) → 1,1,2,2-tetrachlorodisilane + tetrachlorosilane (10026-04-7,53609-55-5) + 1,1,1,2,2-pentachlorodisilane (31411-98-0) + but-2-enyltrichlorosilane (18147-55-2)

Guidance literature:

byproducts: 1,1-dichloro-1-silacyclopent-3-ene, 1-chloro-1-silacyclopent-3-ene; copyrolysis, quartz tube (560°C, retention time 30 s, yields of products depending on temperature (350 to 600°C)), product condensing; products not isolated, reaction monitoring by mass spectroscopy;

DOI:10.1007/BF02494755

upstream raw materials:

trichlorosilane

buta-1,3-diene

3-Chloro-2-methylpropene

Downstream raw materials:

2-Butenyltrimethoxysilane

(1R,2S)-2-methyl-1-phenylbut-3-en-1-ol

(1R,2R)-2-methyl-1-phenylbut-3-en-1-ol

(3-phenylbutyl)trichlorosilane