4-Nitro-2'-carboxybiphenyl

Base Information

• Chemical Name: 4-Nitro-2'-carboxybiphenyl
• CAS No.: 62199-60-4
• Molecular Formula: C13H9NO4
• Molecular Weight: 243.219
• Mol file: 62199-60-4.mol

Synonyms:4-Nitro-(1,1'-biphenyl)-2-carboxylic acid;4-Nitro-biphenyl-2-carbonsaeure;4-Nitro-2-biphenylcarboxylic acid;2-phenyl-5-nitrobenzoic acid;(1,1'-Biphenyl)-2-carboxylic acid,4-nitro;4-nitrobiphenyl-2-carboxylic acid;4-Nitrobiphenyl-carbonsaeure-(2);2-phenyl-4-nitrobenzoic acid;

Chemical Property of 4-Nitro-2'-carboxybiphenyl

Chemical Property:

• Vapor Pressure: 2.31E-07mmHg at 25°C
• Boiling Point: 407.2°Cat760mmHg
• Flash Point: 174.4°C
• PSA: 83.12000
• Density: 1.358g/cm³
• LogP: 3.48320

Purity/Quality:

99% ^*data from raw suppliers

4-Nitrobiphenyl-2-carboxylic acid 95% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-Nitro-2'-carboxybiphenyl

There total 15 articles about 4-Nitro-2'-carboxybiphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

4-nitrobiphenyl-2-carbaldehyde (124391-57-7) → 4-Nitro-2-biphenylcarboxylic acid (62199-60-4)

Guidance literature:

With potassium permanganate; In acetone; for 4h; Ambient temperature;

DOI:10.1055/s-1989-27189

Reference yield: 65.0%

chlorobenzene (108-90-7) + 3-nitrobenzoic acid (121-92-6) → 4-Nitro-2-biphenylcarboxylic acid (62199-60-4)

Guidance literature:

With 3 A molecular sieve; caesium carbonate; palladium diacetate; In N,N-dimethyl-formamide; at 20 - 145 ℃; for 26h;

DOI:10.1021/ja071845e

Reference yield: 65.0%

→ 4-Nitro-2-biphenylcarboxylic acid (62199-60-4)

Guidance literature:

upstream raw materials:

4-nitrobiphenyl-2-carbaldehyde

methyl 4-nitrobiphenyl-2-carboxylate

2-fluoro-5-nitrobenzoic acid

tributylphenylstannane

Downstream raw materials:

1-phenyl-4-nitrobenzene

9-Hydroxy-2-nitrofluorene