2-(Methanesulfonyl)-3-phenylprop-2-en-1-yl carbonochloridate

Base Information

Chemical Name:2-(Methanesulfonyl)-3-phenylprop-2-en-1-yl carbonochloridate
CAS No.:252668-49-8
Molecular Formula:C₁₁H₁₁ClO₄S
Molecular Weight:0
Hs Code.:
DSSTox Substance ID:DTXSID20698600
Mol file:252668-49-8.mol

Synonyms:252668-49-8;DTXSID20698600;2-(Methanesulfonyl)-3-phenylprop-2-en-1-yl carbonochloridate

Suppliers and Price of 2-(Methanesulfonyl)-3-phenylprop-2-en-1-yl carbonochloridate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of 2-(Methanesulfonyl)-3-phenylprop-2-en-1-yl carbonochloridate

Chemical Property:

XLogP3:2.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:5
Exact Mass:274.0066577
Heavy Atom Count:17
Complexity:388

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CS(=O)(=O)C(=CC1=CC=CC=C1)COC(=O)Cl

Technology Process of 2-(Methanesulfonyl)-3-phenylprop-2-en-1-yl carbonochloridate

There total 2 articles about 2-(Methanesulfonyl)-3-phenylprop-2-en-1-yl carbonochloridate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.4%

: 75-44-5
phosgene

: 197244-90-9
(E)-2-(methylsulfonyl)-3-phenyl-2-propenyl alcohol

: 252668-49-8
(E)-2-(methylsulfonyl)-3-phenyl-2-propenyl chloroformate

Guidance literature:: In tetrahydrofuran; at 20 ℃;
DOI:10.1021/jo990541a

Reference yield:

: (E)-3-bromo-2-(methylsulfonyl)-1-phenyl-1-propene

: 252668-49-8
(E)-2-(methylsulfonyl)-3-phenyl-2-propenyl chloroformate

Guidance literature:: Multi-step reaction with 2 steps

1: 80.2 percent / sodium formate; H₂O / methanol / 6 h / Heating

2: 86.4 percent / tetrahydrofuran / 20 °C

With water; sodium formate; In tetrahydrofuran; methanol; 1: Substitution / 2: Substitution;
DOI:10.1021/jo990541a