Formic acid 1,1-dimethylpropyl ester

Base Information

• Chemical Name: Formic acid 1,1-dimethylpropyl ester
• CAS No.: 757-88-0
• Molecular Formula: C6H12O2
• Molecular Weight: 116.16
• Mol file: 757-88-0.mol

Synonyms:Formic acid 1,1-dimethylpropyl ester

Chemical Property of Formic acid 1,1-dimethylpropyl ester

Chemical Property:

• Vapor Pressure: 16.1mmHg at 25°C
• Melting Point: -83.5°C (estimate)
• Refractive Index: 1.3952
• Boiling Point: 119.2°C at 760 mmHg
• Flash Point: 13.3°C
• PSA: 26.30000
• Density: 0.884g/cm³
• LogP: 1.98390

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Formic acid 1,1-dimethylpropyl ester

There total 3 articles about Formic acid 1,1-dimethylpropyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

tert-Amyl methyl ether (994-05-8) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + 2-methyl-2-butanol nitrate (21823-36-9) + tert-pentyl formate (757-88-0)

Guidance literature:

With nitrate radical; In gas; at -16.1 - 89.9 ℃; under 750.06 Torr; Mechanism; Kinetics;

DOI:10.1021/j100074a015

Reference yield:

tert-Amyl methyl ether (994-05-8) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + acetic acid methyl ester (79-20-9) + tert-pentyl formate (757-88-0) + acetaldehyde (75-07-0,9002-91-9) + acetone (67-64-1) + 3-methoxy-3-methylbutanal (181134-54-3)

Guidance literature:

With methyl nitrite; hexane; nitrogen(II) oxide; at 24.9 ℃; Rate constant; Product distribution; Mechanism; Irradiation; var. of reagent;

DOI:10.1002/kin.550270505

Reference yield:

di-tert-pentyloxymethane (54699-28-4) → methylbutane (78-78-4) + tert-pentyl formate (757-88-0)

Guidance literature:

With di-tert-butyl peroxide; at 130 ℃; Mechanism;

upstream raw materials:

tert-Amyl methyl ether

di-tert-pentyloxymethane

Downstream raw materials:

2-methyl-but-2-ene

formic acid

Refernces

• 1、 Langer, Sarka,Ljundstroem, Evert. "Reaction of the Nitrate Radical with Some Potential Automotive Fuel Additives. A Kinetic and Mechanistic Study". . p. 5906 - 5912. Retrieved 2007/10/02.