Methyl 4-bromo-2-(trifluoromethyl)benzoate

Base Information

• Chemical Name: Methyl 4-bromo-2-(trifluoromethyl)benzoate
• CAS No.: 957207-58-8
• Molecular Formula: C9H6BrF3O2
• Molecular Weight: 283.045
• Hs Code.: 2916399090
• Mol file: 957207-58-8.mol

Synonyms:Methyl 4-bromo-2-(trifluoromethyl)benzoate;4-Bromo-2-(trifluoromethyl)benzoic acid methyl ester

Chemical Property of Methyl 4-bromo-2-(trifluoromethyl)benzoate

Chemical Property:

• Vapor Pressure: 0.00548mmHg at 25°C
• Boiling Point: 274.2°C at 760 mmHg
• Flash Point: 119.6°C
• PSA: 26.30000
• Density: 1.598g/cm³
• LogP: 3.25450
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

97% ^*data from raw suppliers

Methyl4-Bromo-2-(trifluoromethyl)benzoate ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methyl 4-bromo-2-(trifluoromethyl)benzoate

There total 6 articles about Methyl 4-bromo-2-(trifluoromethyl)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

methanol (67-56-1) + 4-bromo-2-(trifluoromethyl)benzoic acid (320-31-0) → methyl 4-bromo-2-(trifluoromethyl) benzoate (957207-58-8)

Guidance literature:

With hydrogenchloride; Reflux;

Reference yield:

iodopentafluorobenzene bis(trifluoroacetate) (14353-88-9) + 4-methoxycarbonylphenyl bromide (619-42-1) → 4-bromo-3-trifluoromethylbenzoic acid methyl ester (107317-58-8) + methyl 4-bromo-2-(trifluoromethyl) benzoate (957207-58-8)

Guidance literature:

With tris(2,2-bipyridine)ruthenium(II) hexafluorophosphate; In acetonitrile; at 35 ℃; for 12h; Overall yield = 59 %Spectr.; Irradiation; Inert atmosphere;

DOI:10.1021/acscatal.7b03990

Reference yield:

4-methoxycarbonylphenyl bromide (619-42-1) + trifluoroacetic acid (76-05-1) → 4-bromo-3-trifluoromethylbenzoic acid methyl ester (107317-58-8) + methyl 4-bromo-2-(trifluoromethyl) benzoate (957207-58-8)

Guidance literature:

With dipotassium peroxodisulfate; sulfuric acid; sodium carbonate; silver carbonate; In dichloromethane; at 120 ℃; for 10h; Overall yield = 53 %Spectr.; Schlenk technique; Sealed tube;

DOI:10.1021/ol503189j

upstream raw materials:

methanol

4-bromo-2-(trifluoromethyl)benzoic acid

4-bromo-2-(trifluoromethyl)benzonitrile

4-bromobenzenecarbonitrile

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