6-O-Methacryloyl-1,2:3,4-di-O-isopropylidine-D-galactopyranose

Base Information

• Chemical Name: 6-O-Methacryloyl-1,2:3,4-di-O-isopropylidine-D-galactopyranose
• CAS No.: 2715-36-8
• Molecular Formula: C16H24O7
• Molecular Weight: 328.36
• Mol file: 2715-36-8.mol

Synonyms:6-O-Methacryloyl-1,2:3,4-di-O-isopropylidene-alpha-D-galactopyranose;6-O-Methacryloyl-1,2:3,4-di-O-isopropylidine-D-galactopyranose;Diisopropylidenegalactose 6-methacrylate;1,2:3,4-Di-O-isopropylidene-6-O-methacryloyl-alpha-D-galactopyranose

Chemical Property of 6-O-Methacryloyl-1,2:3,4-di-O-isopropylidine-D-galactopyranose

Chemical Property:

• PSA: 72.45000
• LogP: 1.50220
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,2:3,4-Di-O-isopropylidene-6-O-methacryloyl-α-D-galactopyranose ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: This monomer can be used to make macromolecules containing carbohydrate moieties. Controlled Radical Polymerization; such as NMP; RAFT; or ATRP; is commonly employed to synthesize well-defined glycopolymers.

Technology Process of 6-O-Methacryloyl-1,2:3,4-di-O-isopropylidine-D-galactopyranose

There total 6 articles about 6-O-Methacryloyl-1,2:3,4-di-O-isopropylidine-D-galactopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose (4064-06-6) + Methacryloyl chloride (920-46-7,26937-45-1) → 6-O-methacryloyl-1,2:3,4-di-O-isopropylidene-D-galactopyranose (2715-36-8)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1039/c3ra43497d

Reference yield: 60.0%

poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) + 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose (4064-06-6) → 6-O-methacryloyl-1,2:3,4-di-O-isopropylidene-D-galactopyranose (2715-36-8)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20 ℃;

DOI:10.1002/pola.26012

Reference yield:

α-D-galactopyranose (3646-73-9) + acetone (67-64-1) + Methacryloyl chloride (920-46-7,26937-45-1) → 6-O-methacryloyl-1,2:3,4-di-O-isopropylidene-D-galactopyranose (2715-36-8)

Guidance literature:

α-D-galactopyranose; acetone; With sulfuric acid; at 20 ℃; for 1h; Cooling with ice;

Methacryloyl chloride; With triethylamine; In tetrahydrofuran; at 20 ℃; for 72h; Cooling with ice;

upstream raw materials:

1,2:3,4-di-O-isopropylidene-α-D-galactopyranose

Methacryloyl chloride

poly(methacrylic acid)

α-D-galactopyranose

Downstream raw materials:

6-O-methacryloyl-D-galactose