6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE

Base Information

• Chemical Name: 6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE
• CAS No.: 54325-28-9
• Molecular Formula: C25H26O6
• Molecular Weight: 422.478
• Hs Code.: 2932999099
• Mol file: 54325-28-9.mol

Synonyms:6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE;6-O-TRITYL-ALPHA-D-GLUCOPYRANOSE;(2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol

Chemical Property of 6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE

Chemical Property:

• Boiling Point: 595.6±50.0 °C(Predicted)
• PKA: 12.09±0.70(Predicted)
• PSA: 99.38000
• Density: 1.332±0.06 g/cm3(Predicted)
• LogP: 1.79500
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C

Purity/Quality:

97% ^*data from raw suppliers

(2S,3R,4S,5S,6R)-6-((Trityloxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetraol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE

There total 14 articles about 6-O-TRIPHENYLMETHYL-ALPHA-D-GLUCOPYRANOSE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

D-Galactose (10257-28-0) + trityl chloride (76-83-5) → (3R,4S,5R,6R)-6-(trityloxymethyl)tetrahydropyran-2,3,4,5-tetrol (54325-28-9)

Guidance literature:

With pyridine; at 50 ℃; for 48h; Inert atmosphere;

DOI:10.1016/j.carres.2011.02.014

Reference yield: 94.0%

D-Glucose (2280-44-6) + trityl chloride (76-83-5) → 6-O-trityl-D-glucopyranose (54325-28-9)

Guidance literature:

In pyridine; at 75 ℃; for 18h;

DOI:10.1016/j.tet.2007.07.027

Reference yield: 89.0%

aldehydo-L-Galactose (15572-79-9) + trityl chloride (76-83-5) → (3R,4S,5R,6R)-6-(trityloxymethyl)tetrahydropyran-2,3,4,5-tetrol (54325-28-9)

Guidance literature:

With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane; at 20 ℃; for 24h;

upstream raw materials:

D-glucose

trityl chloride

D-Glucose

alpha-D-glucopyranose

Downstream raw materials:

1,2,3,4-tetra-O-acetyl-6-O-triphenylmethyl-α-D-glucopyranose

1,2,3,4-tetra-O-acetyl-6-O-trityl-β-D-glucopyranose

1,2,3,4-tetra-O-acetyl-6-O-[4-(10-undecenyloxy)benzoyl]-β-D-glucose

1,2,3,4-tetra-O-acetyl-β-D-glucopyranose