ASINEX-REAG BAS 10152054

Base Information

• Chemical Name: ASINEX-REAG BAS 10152054
• CAS No.: 89536-71-0
• Molecular Formula: C14H12O2
• Molecular Weight: 212.248
• Hs Code.: 2912499000
• Mol file: 89536-71-0.mol

Synonyms:ASINEX-REAG BAS 10152054;TIMTEC-BB SBB011271

Chemical Property of ASINEX-REAG BAS 10152054

Chemical Property:

• PSA: 26.30000
• LogP: 3.17470

Purity/Quality:

97% ^*data from raw suppliers

2-methoxy-5-phenylbenzaldehyde ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ASINEX-REAG BAS 10152054

There total 11 articles about ASINEX-REAG BAS 10152054 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.8%

5-bromo-2-methoxybenzaldehyde (25016-01-7) + phenylboronic acid (98-80-6) → 4-methoxy-[1,1′-biphenyl]-3-carbaldehyde (89536-71-0)

Guidance literature:

5-bromo-2-methoxybenzaldehyde; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In 1,2-dimethoxyethane; at 20 ℃; for 0.166667h; Inert atmosphere;

phenylboronic acid; With sodium carbonate; In 1,2-dimethoxyethane; water; at 110 ℃; for 24h; Inert atmosphere;

DOI:10.3390/molecules26133821

Reference yield: 94.0%

Dichloromethyl methyl ether (4885-02-3) + 4-methoxylbiphenyl (613-37-6) → 4-methoxy-[1,1′-biphenyl]-3-carbaldehyde (89536-71-0)

Guidance literature:

With titanium tetrachloride; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/jo101709n

Reference yield: 91.0%

bromobenzene (108-86-1,52753-63-6) + 3-formyl-4-methoxyphenylboronic acid (121124-97-8) → 4-methoxy-[1,1′-biphenyl]-3-carbaldehyde (89536-71-0)

Guidance literature:

With potassium carbonate; In water; isopropyl alcohol; at 20 ℃; for 0.5h; Catalytic behavior; Green chemistry;

DOI:10.1007/s10562-021-03755-w

upstream raw materials:

2-hydroxy-5-phenylbenzaldehyde

dimethyl sulfate

methyl iodide

4-methoxylbiphenyl

Downstream raw materials:

4-(4-methoxy-biphenyl-3-ylmethylene)-2-phenyl-4H-oxazol-5-one

2,3-Dibromo-1-(2-hydroxy-phenyl)-3-(4-methoxy-biphenyl-3-yl)-propan-1-one

2,3-Dibromo-1-(2-hydroxy-biphenyl-3-yl)-3-(4-methoxy-biphenyl-3-yl)-propan-1-one

2,3-Dibromo-1-(4-hydroxy-biphenyl-3-yl)-3-(4-methoxy-biphenyl-3-yl)-propan-1-one