3,5-Dibenzyloxy-trans-beta-nitrostyrene

Base Information

Chemical Name:3,5-Dibenzyloxy-trans-beta-nitrostyrene
CAS No.:86255-44-9
Molecular Formula:C22H19NO4
Molecular Weight:361.395
Hs Code.:2909309090
European Community (EC) Number:620-705-2
Wikidata:Q76422077
Mol file:86255-44-9.mol

Synonyms:86255-44-9;Benzene, 1-[(1E)-2-nitroethenyl]-3,5-bis(phenylmethoxy)-;3,5-Dibenzyloxy-trans-beta-nitrostyrene;AKOS015889384;3,5-Dibenzyloxy-trans- beta -nitrostyrene

Suppliers and Price of 3,5-Dibenzyloxy-trans-beta-nitrostyrene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
1-(3,5-DIBENZYLOXYPHENYL)-2-NITROETHENE 95.00%
5MG
$ 497.27

Total 4 raw suppliers

Chemical Property of 3,5-Dibenzyloxy-trans-beta-nitrostyrene

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Melting Point:108-112 °C(lit.)
Boiling Point:549.356°C at 760 mmHg
Flash Point:220.453°C
PSA：64.28000
Density:1.221g/cm³
LogP:5.61520
XLogP3:5.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:7
Exact Mass:361.13140809
Heavy Atom Count:27
Complexity:433

Purity/Quality:

99% ^*data from raw suppliers

1-(3,5-DIBENZYLOXYPHENYL)-2-NITROETHENE 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xi,N
Hazard Codes:Xi,N
Statements: 41-50/53
Safety Statements: 26-36/37/39-60-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)COC2=CC(=CC(=C2)C=C[N+](=O)[O-])OCC3=CC=CC=C3
Isomeric SMILES:C1=CC=C(C=C1)COC2=CC(=CC(=C2)/C=C/[N+](=O)[O-])OCC3=CC=CC=C3

Technology Process of 3,5-Dibenzyloxy-trans-beta-nitrostyrene

There total 4 articles about 3,5-Dibenzyloxy-trans-beta-nitrostyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 75-52-5
nitromethane

: 14615-72-6
3,5-dibenzyloxybenzaldehyde

: 86255-44-9
(E)-(((5-(2-nitrovinyl)-1,3-phenylene)bis(oxy))bis(methylene))dibenzene

Guidance literature:: With ammonium acetate; for 1.5h; Reflux;
DOI:10.1021/jo2009615

Reference yield:

: 24131-31-5
3,5-dibenzyloxybenzyl alcohol

: 86255-44-9
(E)-(((5-(2-nitrovinyl)-1,3-phenylene)bis(oxy))bis(methylene))dibenzene

Guidance literature:: Multi-step reaction with 2 steps

1: 84 percent / MnO₂ / CH₂Cl₂ / Ambient temperature

2: 60 percent / ammonium acetate, gl. AcOH / 5 h / Heating

With ammonium acetate; manganese(IV) oxide; acetic acid; In dichloromethane;
DOI:10.1021/jm960449w

Reference yield:

: 29654-55-5
5-(hydroxymethyl)benzene-1,3-diol

: 86255-44-9
(E)-(((5-(2-nitrovinyl)-1,3-phenylene)bis(oxy))bis(methylene))dibenzene

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / K₂CO₃ / dimethylformamide / 3 h / Heating

2: 84 percent / MnO₂ / CH₂Cl₂ / Ambient temperature

3: 60 percent / ammonium acetate, gl. AcOH / 5 h / Heating

With ammonium acetate; manganese(IV) oxide; potassium carbonate; acetic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/jm960449w