Dibenzyl-(2-isopropenyl-phenyl)-amine

Base Information

• Chemical Name: Dibenzyl-(2-isopropenyl-phenyl)-amine
• CAS No.: 81051-11-8
• Molecular Formula: C23H23N
• Molecular Weight: 313.44
• DSSTox Substance ID: DTXSID30701336
• Wikidata: Q82632945
• Mol file: 81051-11-8.mol

Synonyms:81051-11-8;DIBENZYL-(2-ISOPROPENYL-PHENYL)-AMINE;N,N-dibenzyl-2-(prop-1-en-2-yl)aniline;DTXSID30701336;Dibenzyl-(2-isopropenyl-phenyl)amine;DIBENZYL-(2-ISOPROPENYLPHENYL)AMINE

Chemical Property of Dibenzyl-(2-isopropenyl-phenyl)-amine

Chemical Property:

• PSA: 3.24000
• LogP: 5.92650
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 313.183049738
• Heavy Atom Count: 24
• Complexity: 356

Purity/Quality:

97% ^*data from raw suppliers

DIBENZYL-(2-ISOPROPENYL-PHENYL)AMINE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(=C)C1=CC=CC=C1N(CC2=CC=CC=C2)CC3=CC=CC=C3

Technology Process of Dibenzyl-(2-isopropenyl-phenyl)-amine

There total 1 articles about Dibenzyl-(2-isopropenyl-phenyl)-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

2-isopropenylaniline (52562-19-3) + benzyl bromide (100-39-0) → o-isopropenyl-N,N-dibenzylaniline (81051-11-8)

Guidance literature:

With potassium carbonate; potassium iodide; In acetonitrile; at 90 ℃; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/chem.201804777

Reference yield: 69.0%

o-isopropenyl-N,N-dibenzylaniline (81051-11-8) + platinum(II) bromde (13455-12-4) → Pt(IBN)Br2 IBN=o-isopropenyl-N,N-dibenzylaniline

Guidance literature:

In chloroform; PtCl2 stirred in refluxing CHCl3, added ligand, refluxed for 2 h, filtered, concd., MeOH added, placed at -20°C overnight; filtered, further crystals collected by partial evapn. of filtrate, washed with MeOH, air dried, elem. anal.;

DOI:10.1016/S0022-328X(00)89058-0

Reference yield: 67.0%

o-isopropenyl-N,N-dibenzylaniline (81051-11-8) + platinum(II) chloride (10025-65-7) → Pt(IBN)Cl2 IBN=o-isopropenyl-N,N-dibenzylaniline

Guidance literature:

In chloroform; PtCl2 stirred in refluxing CHCl3, added ligand, refluxed for 2 h, filtered, concd., MeOH added, placed at -20°C overnight; filtered, further crystals collected by partial evapn. of filtrate, washed with MeOH, air dried, elem. anal.;

DOI:10.1016/S0022-328X(00)89058-0

upstream raw materials:

2-isopropenylaniline

benzyl bromide