3-CHLOROSTYRENE POLYMER

Base Information

• Chemical Name: 3-CHLOROSTYRENE POLYMER
• CAS No.: 26100-04-9
• Molecular Formula: C8H7Cl
• Molecular Weight: 138.597
• Mol file: 26100-04-9.mol

Synonyms:3-CHLOROSTYRENE POLYMER;POLY(3-CHLOROSTYRENE)

Chemical Property of 3-CHLOROSTYRENE POLYMER

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-CHLOROSTYRENE POLYMER

There total 37 articles about 3-CHLOROSTYRENE POLYMER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

ethene (74-85-1) + 3-iodochlorobenzene (625-99-0) → 3-Chlorostyrene (2039-85-2,26100-04-9)

Guidance literature:

With N-Methyldicyclohexylamine; palladium diacetate; tetra-(n-butyl)ammonium iodide; tri tert-butylphosphoniumtetrafluoroborate; In methanol; toluene; at 130 ℃; for 0.333333h; under 7500.75 Torr;

DOI:10.1002/cctc.201200778

Reference yield: 71.0%

methyl-triphenylphosphonium iodide (2065-66-9) + m-Chlorobenzaldehyde (587-04-2) → 3-Chlorostyrene (2039-85-2,26100-04-9)

Guidance literature:

With potassium carbonate; In 1,4-dioxane; water; at 95 ℃; for 12h; Inert atmosphere;

Reference yield: 63.0%

1-(3-chlorophenyl)-2-propyn-1-ol (29805-12-7) + benzoic acid (65-85-0,8013-63-6) → 1-(3-chlorophenyl)-2-oxopropyl benzoate (1241573-12-5) + 3-Chlorostyrene (2039-85-2,26100-04-9)

Guidance literature:

With RuCl2(η-C6H6)(TPPMS); In water; at 100 ℃; for 6h; Inert atmosphere;

DOI:10.1039/b914774h

upstream raw materials:

m-chlorocumene

m-Chlorocinnamic acid

acetic anhydride

m-Chlorobenzaldehyde

Downstream raw materials:

5-(3-chloro-phenyl)-2-[1-(3-chloro-phenyl)-2-nitro-ethoxy]-3,3-dinitro-isoxazolidine

2-bromo-1-(3-chlorophenyl)-1,1-dimethoxyethane

3-chloroethylbenzene

3-chloro-α-methylphenylacetaldehyde

Refernces

• 1、 Dong, Bingbing,Lu, Jiansha,Bao, Honghao,Zhang, Yuanyuan,Liu, Yingguo,Leng, Yuting. "Copper-Catalyzed Sulfonylation of Cyclobutanone Oxime Esters with Sulfonyl Hydrazides". supporting information. p. 3769 - 3776. Retrieved 2021/07/14.
• 2、 Geng, Jiao,Hu, Xingbang,Liu, Qiang,Wu, Youting,Yang, Liu,Yao, Chenfei. "Controlling the Lewis Acidity and Polymerizing Effectively Prevent Frustrated Lewis Pairs from Deactivation in the Hydrogenation of Terminal Alkynes". . p. 3685 - 3690. Retrieved 2021/05/31.