1-broMo-4-((4-vinylbenzyl)oxy)benzene

Base Information

• Chemical Name: 1-broMo-4-((4-vinylbenzyl)oxy)benzene
• CAS No.: 92434-51-0
• Molecular Formula: C15H13BrO
• Molecular Weight: 289.172
• Mol file: 92434-51-0.mol

Synonyms:1-broMo-4-((4-vinylbenzyl)oxy)benzene;1-Bromo-4-[(4-ethenylphenyl)methoxy]benzene

Chemical Property of 1-broMo-4-((4-vinylbenzyl)oxy)benzene

Chemical Property:

• PSA: 9.23000
• LogP: 4.67110

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-broMo-4-((4-vinylbenzyl)oxy)benzene

There total 1 articles about 1-broMo-4-((4-vinylbenzyl)oxy)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-bromo-phenol (106-41-2) + 4-Vinylbenzyl chloride (1592-20-7,29296-32-0) → 1-bromo-4-((4-vinylbenzyl)oxy)benzene (92434-51-0)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide;

DOI:10.1016/j.dyepig.2020.109122

Reference yield:

boric acid tributyl ester (688-74-4) + 1-bromo-4-((4-vinylbenzyl)oxy)benzene (92434-51-0) → C15H15BO3

Guidance literature:

1-bromo-4-((4-vinylbenzyl)oxy)benzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 3h; Inert atmosphere;

boric acid tributyl ester; In tetrahydrofuran; at 20 ℃; for 15h;

Reference yield:

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1-bromo-4-((4-vinylbenzyl)oxy)benzene (92434-51-0) + 1,2-bis(dichlorophosphino)ethane (28240-69-9) → (((CH2CHC6H4CH2OC6H4)2PCH2)2)PtCl2 (635684-06-9)

Guidance literature:

With n-butyllithium; copper(l) chloride; In tetrahydrofuran; hexane; dichloromethane; to arylbromide in THF at -78°C soln. n-BuLi in hexane was added, -78°C for 1 h, CuCl was added, 15 min, soln. Cl2PCH2CH2PCl2 in THF was added, -78°C for 24 h under Ar, (COD)PtCl2 in CH2Cl2 was added, 1 h at room temp.; volatiles were removed in vacuo, residue was taken up in CH2Cl2, filtered, and evapd., residue was washed with Et2O;

DOI:10.1021/om0340387

upstream raw materials:

4-bromo-phenol

4-Vinylbenzyl chloride

Downstream raw materials:

(((CH₂CHC₆H₄CH₂OC₆H₄)2PCH₂)2)PtCl₂