(C₆F₅)2HB*SMe₂

Base Information

Chemical Name:(C₆F₅)2HB*SMe₂
CAS No.:1000399-06-3
Molecular Formula:C₁₄H₇BF₁₀S
Molecular Weight:408.071
Hs Code.:

(C<sub>6</sub>F<sub>5</sub>)2HB*SMe<sub>2</sub>

Synonyms:(C₆F₅)2HB*SMe₂

Suppliers and Price of (C₆F₅)2HB*SMe₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (C₆F₅)2HB*SMe₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (C₆F₅)2HB*SMe₂

There total 4 articles about (C₆F₅)2HB*SMe₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 75-18-3
dimethylsulfide

: 4Mg⁽²⁺⁾*6O(C₂H₅)2*4.8Br^(1-)*1.2Cl^(1-)*2H₂B(C₆F₅)2^(1-)*C₆H₅CH₃*2CHCl₃=(Mg₂(O(C₂H₅)2)3Br_2.4Cl_0.6(H₂B(C₆F₅)2))2*C₇H₈*2CHCl₃

: 1000399-06-3
(C₆F₅)2HB*SMe₂

Guidance literature:: With Me₃SiCl; In further solvent(s); under N2; Me3SiCl added at room temp. to stirred soln. of Mg complex in SMe2; stirred for 90 min; volatiles removed under reduced pressure; suspended in benzene; filtered; ppt. extracted with benzene; combined org. phases freeze dried in vac.; detd. by (1)H, (11)B and (19)F NMR spectra;
DOI:10.1021/om200186w

Reference yield: 54.0%

: 6867-36-3
ether adduct of tris(pentafluorophenyl)boron

: 13292-87-0
dimethylsulfide borane complex

: 1000399-06-3
(C₆F₅)2HB*SMe₂

: (C₆F₅)3B*SMe₂

Guidance literature:: ether adduct of tris(pentafluorophenyl)boron; dimethylsulfide borane complex; In light petroleum; Inert atmosphere;

With dimethylsulfide; In light petroleum; Inert atmosphere;
DOI:10.1021/om100152v

Reference yield: 54.0%

: 13292-87-0
dimethyl sulfide borane

: tris(pentafluorophenyl)borane*(diethyl ether)

: 1000399-06-3
(C₆F₅)2HB*SMe₂

Guidance literature:: In light petroleum; byproducts: (C6F5)3B*SMe2; (N2); using Schlenk techniques; addn. of H3B*SMe2 (1 equiv.) to soln. of(C6F5)3B*OEt2 (2 equiv.) in light petroleum, pptn. of oil, stirring for a few minutes, addn. of excess of Me2S; sepn. of oil by filtration, cooling to 0°C, pptn., filtration, concn., cooling to -25°C, crystn.; elem. anal.;
DOI:10.1021/om100152v