[2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II)

Base Information

• Chemical Name: [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II)
• CAS No.: 1420299-84-8
• Molecular Formula: C₄₂H₃₇ClF₃PRuS
• Molecular Weight: 798.314

Synonyms:[2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II)

Chemical Property of [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II)

Chemical Property:

Purity/Quality:

98%,99%, ^*data from raw suppliers

Chloro[(1,2,3,4,5,6-η)-2,2'',4,4'',6,6''-hexamethyl[1,1':3',1''-terphenyl]-2'-thiolato-κS][tris(4-fluorophenyl)phosphine-κP]ruthenium(II) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
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Technology Process of [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II)

There total 1 articles about [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

[ruthenium(II)(η6-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]2 (52462-29-0) + 2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol (157590-41-5) + P(p-C6H4F)3 (18437-78-0) → [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II) (1420299-84-8)

Guidance literature:

2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol; With n-butyllithium; In hexane; at 0 ℃; for 0.5h;

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; In tetrahydrofuran; hexane; at 0 - 20 ℃; for 3h;

P(p-C₆H₄F)3; In toluene; at 65 ℃; for 15h;

DOI:10.1021/ja311398j

Reference yield: 98.0%

sodium tetrakis(pentafluorophenyl)-borate (2797-28-6) + [2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II) (1420299-84-8) → 2,6-η6:η1-bis(2’,4’,6’-trimethylphenyl)phenylthiolato(tris(4’-fluorophenyl)phosphino)ruthenium(II) tetrakis(pentafluorophenyl)borate

Guidance literature:

In dichloromethane; at 40 ℃; for 16h; Glovebox; Inert atmosphere;

DOI:10.1021/acs.organomet.6b00801

Reference yield: 94.0%

[2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]chlorido[tris(4-fluorophenyl)phosphine]ruthenium(II) (1420299-84-8) + C6H16B11Br6(1-)*Na(1+) → C42H37F3PRuS(1+)*C6H16B11Br6(1-)

Guidance literature:

at 80 ℃; for 17h; Glovebox; Inert atmosphere;

DOI:10.1021/acs.organomet.6b00801

upstream raw materials:

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

2,2'',4,4'',6,6''-hexamethyl-[1,1':3',1''-terphenyl]-2'-thiol

P(p-C₆H₄F)3

Downstream raw materials:

[2,6-η6:η1-bis(2,4,6-trimethylphenyl)phenylthiolato]tris(4-fluorophenyl)phosphineruthenium(II)tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

C₈₄H₇₄ClF₆P₂Ru₂S₂⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-)

C₄₂H₃₈F₃PRuS

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