3-methyl-1-phenylhexa-1,5-dien-3-ol

Base Information

Chemical Name:3-methyl-1-phenylhexa-1,5-dien-3-ol
CAS No.:866565-26-6
Molecular Formula:C₁₃H₁₆O
Molecular Weight:188.269
Hs Code.:

Synonyms:3-methyl-1-phenylhexa-1,5-dien-3-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 3-methyl-1-phenylhexa-1,5-dien-3-ol

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Technology Process of 3-methyl-1-phenylhexa-1,5-dien-3-ol

There total 3 articles about 3-methyl-1-phenylhexa-1,5-dien-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 106-95-6
allyl bromide

: 122-57-6
1-Phenylbut-1-en-3-one

: 866565-26-6
3-methyl-1-phenylhexa-1,5-dien-3-ol

: 785778-74-7
(S)-(?)-3-methyl-1-phenylhexa-1,5-dien-3-ol

Guidance literature:: allyl bromide; With manganese; chromium(III) bromide; C₃₆H₃₉BN₃O₃^(1-)*H⁽¹⁺⁾; triethylamine; at 20 ℃; for 1h; Inert atmosphere;

1-Phenylbut-1-en-3-one; With chloro-trimethyl-silane; In tetrahydrofuran; at 20 ℃; for 20h; Inert atmosphere;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; optical yield given as %ee; enantioselective reaction;
DOI:10.1002/adsc.200900595

Reference yield:

: 7393-43-3
tetraallyl tin

: 122-57-6
1-Phenylbut-1-en-3-one

: 866565-26-6
3-methyl-1-phenylhexa-1,5-dien-3-ol

: 785778-74-7
(S)-(?)-3-methyl-1-phenylhexa-1,5-dien-3-ol

Guidance literature:: With titanium(IV) isopropylate; isopropyl alcohol; In dichloromethane; at 20 ℃; Overall yield = 85 %; Overall yield = 32.3 mg; enantioselective reaction; Glovebox; Inert atmosphere;
DOI:10.1002/chem.201400204

Reference yield:

: 54655-41-3
B-allyl-1,3,2-dioxaborinane

: 122-57-6
1-Phenylbut-1-en-3-one

: 866565-26-6
3-methyl-1-phenylhexa-1,5-dien-3-ol

: 785778-74-7
(S)-(?)-3-methyl-1-phenylhexa-1,5-dien-3-ol

Guidance literature:: B-allyl-1,3,2-dioxaborinane; With (S)-2,15-dibromotetraphenylene-1,16-diol; In tert-butyl alcohol; at 25 ℃; for 0.166667h; Schlenk technique; Inert atmosphere;

1-Phenylbut-1-en-3-one; In tert-butyl alcohol; at 25 ℃; Overall yield = 90 %; Overall yield = 17 mg; enantioselective reaction; Schlenk technique; Inert atmosphere;
DOI:10.1021/acs.joc.8b02475