Tetraallyltin

Base Information

• Chemical Name: Tetraallyltin
• CAS No.: 7393-43-3
• Molecular Formula: C12H20Sn
• Molecular Weight: 283.001
• Hs Code.: 29310099
• European Community (EC) Number: 230-987-5
• UNII: 68PK869PUT
• DSSTox Substance ID: DTXSID80224580
• Mol file: 7393-43-3.mol

Synonyms:Tetraallyltin;7393-43-3;Tetraallylstannane;tetrakis(prop-2-enyl)stannane;Tetrallylstannane;Stannane, tetra-2-propenyl-;Stannane, tetraallyl-;68PK869PUT;EINECS 230-987-5;AI3-28455;Tetraallyltin, 97%;UNII-68PK869PUT;C12-H20-Sn;DTXSID80224580;TETRA-2-PROPEN-1-YLSTANNANE;TETRAKIS(2-PROPENYL)STANNANE;MFCD00008637;AKOS015838925;STANNANE, TETRA-2-PROPEN-1-YL-;FT-0741852;T2009;D92566;J-524848;Tetraallylstannane, Tetraallyltin, tetrallylstannane

Chemical Property of Tetraallyltin

Chemical Property:

• Appearance/Colour: Clear Colorless liquid
• Vapor Pressure: 0.0708mmHg at 25°C
• Refractive Index: n20/D 1.539(lit.)
• Boiling Point: 236.9 °C at 760 mmHg
• Flash Point: 104.8 °C
• PSA: 0.00000
• Density: 1.179 g/mL at 25 °C
• LogP: 4.17920
• Sensitive.: Air Sensitive
• Water Solubility.: Not miscible in water or difficult to mix.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 284.058703
• Heavy Atom Count: 13
• Complexity: 146

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetraallyltin >97.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25
• Safety Statements: 23-24/25-45-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C=CC[Sn](CC=C)(CC=C)CC=C
• Uses: Applied as allyl transfer reagent.

Technology Process of Tetraallyltin

There total 12 articles about Tetraallyltin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

tin(IV) chloride (7646-78-8) + allylmagnesium bromide (1730-25-2) → tetraallyl tin (7393-43-3)

Guidance literature:

In diethyl ether; at -78 - 20 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.tet.2014.06.006

Reference yield: 75.0%

tin(IV) chloride (7646-78-8) + magnesium (7439-95-4) + 3-chloroprop-1-ene (107-05-1) → tetraallyl tin (7393-43-3)

Guidance literature:

With dibromomethane; In tetrahydrofuran; hexane; reaction of 5.5 mol Mg in THF with a mixture of dibromomethane and allylchloride at 0°C; cooling to -15--20°C; addn. of 5 mol allylchloride and THF within 8 h; stirring for 3 h at room temperature; addn. of 0.72 mol SnCl4 in n-hexane;; heating under reflux for 5 h; addn. of concd. ammoniumchloride soln. under ice-cooling; drying the non-aq. phase with Na2SO4; distillation of solvent; distillation;;

Reference yield: 60.0%

stannic bromide (7789-67-5) + allylmagnesium bromide (1730-25-2) → tetraallyl tin (7393-43-3)

Guidance literature:

In diethyl ether; benzene; reaction in diethyl ether, heating in benzene for 1 h;

upstream raw materials:

allylmagnesium bromide

tin

allyl bromide

tetraphenyltin(IV)

Downstream raw materials:

Methylphenyl-1-naphthylallylsilan

allyllithium

1-(2-pyridinyl)but-3-en-1-ol

(E)-1-phenyl-1,5-hexadien-3-ol