N'-(benzylideneamino)-N,N-diethylethan-1-amine

Base Information

• Chemical Name: N'-(benzylideneamino)-N,N-diethylethan-1-amine
• CAS No.: 1749-16-2
• Molecular Formula: C₁₃H₂₀N₂
• Molecular Weight: 204.315
• Mol file: 1749-16-2.mol

Synonyms:N'-(benzylideneamino)-N,N-diethylethan-1-amine

Chemical Property of N'-(benzylideneamino)-N,N-diethylethan-1-amine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N'-(benzylideneamino)-N,N-diethylethan-1-amine

There total 5 articles about N'-(benzylideneamino)-N,N-diethylethan-1-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

benzaldehyde (100-52-7) + N,N-diethylethylenediamine (100-36-7) → N'-(benzylideneamino)-N,N-diethylethan-1-amine (1749-16-2)

Guidance literature:

With sodium sulfate; In diethyl ether; at 20 ℃; for 2h; Reflux;

DOI:10.1002/ejic.202100185

Reference yield:

N1-benzylidene-N2,N2-dimethylethane-1,2-diamine (23956-51-6) → N'-(benzylideneamino)-N,N-diethylethan-1-amine (1749-16-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; oxygen / acetone / Glovebox

1.2: 0.5 h / 70 °C / Glovebox

2.1: magnesium sulfate / diethyl ether / 2 h / 20 °C / Reflux

With tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; oxygen; magnesium sulfate; In diethyl ether; acetone;

DOI:10.1002/chem.201501003

Reference yield:

benzaldehyde (100-52-7) → N'-(benzylideneamino)-N,N-diethylethan-1-amine (1749-16-2)

Guidance literature:

Multi-step reaction with 3 steps

1.1: sodium sulfate / diethyl ether / 2 h / 20 °C / Reflux

2.1: tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; oxygen / acetone / Glovebox

2.2: 0.5 h / 70 °C / Glovebox

3.1: magnesium sulfate / diethyl ether / 2 h / 20 °C / Reflux

With tetrakis(acetonitrile)copper(I) trifluoromethanesulfonate; oxygen; magnesium sulfate; sodium sulfate; In diethyl ether; acetone;

DOI:10.1002/chem.201501003

upstream raw materials:

benzaldehyde

N,N-diethylethylenediamine

N¹-benzylidene-N²,N²-dimethylethane-1,2-diamine

Downstream raw materials:

N¹-benzylidene-N²,N²-dimethylethane-1,2-diamine

benzaldehyde

salicylaldehyde

1-phenyl-3-morpholino-2-aza-1-butene

Refernces

• 1、 Becker, Jonathan,Gupta, Puneet,Angersbach, Friedrich,Tuczek, Felix,N?ther, Christian,Holthausen, Max C.,Schindler, Siegfried. "Selective Aromatic Hydroxylation with Dioxygen and Simple Copper Imine Complexes". . p. 11735 - 11744. Retrieved 2015/08/11.
• 2、 Nikogosyan, L. L.,Nersesyan, K. A.,Satina, T. Ya.,Panosyan, G. A.,Indzhikyan, M. G.. "SYNTHESIS AND SOME TRANSFORMATIONS OF 1-ARYL-2-AZA-1,3-BUTADIENES". . p. 671 - 675. Retrieved 2007/10/02.