(-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

Base Information

Chemical Name:(-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate
CAS No.:1315179-34-0
Molecular Formula:C₃₃H₃₁NO₄
Molecular Weight:505.613
Hs Code.:

Synonyms:(-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

Suppliers and Price of (-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

There total 1 articles about (-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: C₂₆H₂₆O₄

: 69261-49-0
benzyl formylcarbamate

: 1315128-08-5
phenylmethyl formyl{(2E)-5-[(triphenylmethyl)oxy]pent-2-en-1-yl}carbamate

: 1315179-34-0
(-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

Guidance literature:: With bis(1,5-cyclooctadiene)diiridium(I) dichloride; C₃₈H₃₄NO₄P; 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine; In tetrahydrofuran; at 50 ℃; for 2.5h; enantioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201100649

Reference yield: 97.0%

: 1315179-34-0
(-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

: 1315128-25-6
(+)-phenylmethyl ((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

Guidance literature:: With potassium hydroxide; In methanol; at 20 ℃; for 2h;
DOI:10.1002/chem.201100649

Reference yield:

: 1315179-34-0
(-)-phenylmethyl formyl((1S)-1-{2-[(triphenylmethyl)oxy]ethyl}prop-2-en-1-yl)carbamate

: 1315128-44-9
(+)-methyl (2E,6R)-6-({[(phenylmethyl)oxy]carbonyl}amino)-8-[(triphenylmethyl)oxy]oct-2-enoate

Guidance literature:: Multi-step reaction with 3 steps

1: potassium hydroxide / methanol / 2 h / 20 °C

2: tetrahydrofuran / 2 h / 50 °C / Inert atmosphere

3: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate; N,N-dimethyl-formamide / tetrahydrofuran; water / 20 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate; N,N-dimethyl-formamide; potassium hydroxide; In tetrahydrofuran; methanol; water; 3: Suzuki-Miyaura coupling;
DOI:10.1002/chem.201100649