(PhB(CH₂P^iPr₂)₃)Fe(H)₃(PMe₃)

Base Information

• Chemical Name: (PhB(CH₂P^iPr₂)₃)Fe(H)₃(PMe₃)
• CAS No.: 801221-19-2
• Molecular Formula: C₃₀H₆₅BFeP₄
• Molecular Weight: 616.399
• Mol file: 801221-19-2.mol

Synonyms:(PhB(CH₂P^iPr₂)₃)Fe(H)₃(PMe₃)

Chemical Property of (PhB(CH₂P^iPr₂)₃)Fe(H)₃(PMe₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (PhB(CH₂P^iPr₂)₃)Fe(H)₃(PMe₃)

There total 1 articles about (PhB(CH₂P^iPr₂)₃)Fe(H)₃(PMe₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

[(phenyl)B(CH2P(iPr)2)3(methyl)iron(II)] (801221-16-9) + hydrogen (1333-74-0) + trimethylphosphane (594-09-2) → (PhB(CH2PiPr2)3)Fe(H)3(PMe3) (801221-19-2)

Guidance literature:

In tetrahydrofuran; byproducts: CH4; (N2); Schlenk technique; P ligand was added to soln. of Fe compd. in THF; soln. was degassed; pressurized with H2 (1 atm); soln. was stirred at room temp. for 24 h; evapd. (vac.); dissolved in Et2O; filtered; stored at -25°C underN2; elem. anal.;

DOI:10.1021/ic0488583

Reference yield: 70.0%

(PhB(CH2PiPr2)3)Fe(H)3(PMe3) (801221-19-2) + carbon dioxide (124-38-9,18923-20-1) → (PhB(CH2PiPr2)3)Fe(OCHO)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 12h; under 760.051 Torr; Inert atmosphere; Sealed tube;

DOI:10.1021/ic502508p

Reference yield: 63.0%

ethene (74-85-1) + (PhB(CH2PiPr2)3)Fe(H)3(PMe3) (801221-19-2) → [(C6H5B(CH2P(CH(CH3)2)2)3)Fe(CH2CH3)] (801221-27-2)

Guidance literature:

In tetrahydrofuran; byproducts: PMe3, C2H6; (N2); standard Schlenk technique; soln. of Fe complex in THF was degassed; filled with ethylene (1 atm); stirred overnight; evapd.; dissolved in Et2O; filtered; Et2O removed (vac.); dissolved in Et2O; stored at -25°C; elem. anal.;

DOI:10.1021/ic0488583

upstream raw materials:

[(phenyl)B(CH₂P(iPr)2)3(methyl)iron(II)]

hydrogen

trimethylphosphane

Downstream raw materials:

[(C₆H₅B(CH₂P(CH(CH₃)2)2)3)Fe(CH₂CH₃)]

Refernces