2,4-Decadienal

Base Information

• Chemical Name: 2,4-Decadienal
• CAS No.: 2363-88-4
• Molecular Formula: C10H16O
• Molecular Weight: 152.236
• Hs Code.: 2912190090
• European Community (EC) Number: 219-114-9,246-668-9
• UNII: 3G88X2RK09
• DSSTox Substance ID: DTXSID6024911
• Nikkaji Number: J498.775F,J80.457F,J88.325E,J88.326C
• Wikipedia: (E,E)-2,4-Decadienal
• Wikidata: Q4544759
• Metabolomics Workbench ID: 3455
• ChEMBL ID: CHEMBL443949
• Mol file: 2363-88-4.mol

Synonyms:2,4,7-tridecadienal;2,4-decadienal;2-trans-4-trans-decadienal;2E,7Z-decadienal

Chemical Property of 2,4-Decadienal

Chemical Property:

• Appearance/Colour: Yellow to light orange translucent liquid
• Vapor Pressure: 0.03mmHg at 25°C
• Refractive Index: n20/D 1.515(lit.)
• Boiling Point: 244.6 °C at 760 mmHg
• Flash Point: 102.3 °C
• PSA: 17.07000
• Density: 0.854 g/cm³
• LogP: 2.87800
• Storage Temp.: Amber Vial, -20°C Freezer, Under Inert Atmosphere
• Solubility.: Chloroform (Slightly), DMSO (Sparingly), Ethyl Acetate, Methanol
• XLogP3: 3.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 152.120115130
• Heavy Atom Count: 11
• Complexity: 134

Purity/Quality:

99% ^*data from raw suppliers

trans,trans-2,4-Decadienal ≥89%, FG ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Aldehydes
• Canonical SMILES: CCCCCC=CC=CC=O
• Isomeric SMILES: CCCCC/C=C/C=C/C=O
• Uses: trans,trans-2,4-Decadienal is an aldehyde with a fat flavor aroma characteristic of chicken but has a citrus odor at lower concentrations. trans,trans-2,4-Decadienal can be found in butter, cooked beef, fish, potato chips, roasted peanut, buckwheat and wheat bread crumb.

Technology Process of 2,4-Decadienal

There total 10 articles about 2,4-Decadienal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

(E)-(4-Oxo-2-butenyl)phosphonsaeure-diethylester (110905-37-8) + hexanal (66-25-1) → deca-2,4-dienal (2363-88-4,65909-91-3)

Guidance literature:

With cyclohexylamine; lithium diisopropyl amide; In tetrahydrofuran; at 0 - 25 ℃; for 2h;

DOI:10.1021/jo00306a006

Reference yield:

L-phenylalanine (63-91-2,25191-15-5,658-69-5,67675-33-6) + methyl 13-hydroperoxyoctadeca-9,11-dienoate (14606-80-5,32671-93-5,60900-56-3,90760-87-5,90760-88-6,96192-73-3,101470-44-4,116181-14-7,116181-17-0,134522-67-1,65148-33-6) → 2-pentylfuran (3777-69-3) + α-pyrrole ethylbenzene (17289-34-8) + 2-hexenal (505-57-7) + 2-octen-1-al (2548-87-0,20664-46-4,2363-89-5) + methyl octanate (111-11-5) + deca-2,4-dienal (2363-88-4,65909-91-3) + 2-pentyl-1-phenylethyl-1H-pyrrole + phenylacetaldehyde (122-78-1) + benzaldehyde (100-52-7) + hexanal (66-25-1)

Guidance literature:

at 180 ℃; aq. buffer;

DOI:10.1021/jf801409w

Reference yield:

L-phenylalanine (63-91-2,25191-15-5,658-69-5,67675-33-6) + methyl 13-hydroperoxyoctadeca-9,11,15-trienoate (14606-84-9) → 2-pentylfuran (3777-69-3) + α-pyrrole ethylbenzene (17289-34-8) + 2-hexenal (505-57-7) + 2-octen-1-al (2548-87-0,20664-46-4,2363-89-5) + methyl octanate (111-11-5) + deca-2,4-dienal (2363-88-4,65909-91-3) + 2-pentyl-1-phenylethyl-1H-pyrrole + phenylacetaldehyde (122-78-1) + benzaldehyde (100-52-7) + hexanal (66-25-1)

Guidance literature:

at 180 ℃; aq. buffer;

DOI:10.1021/jf801409w

upstream raw materials:

1,1-diethoxy-oct-2-ene

ethyl vinyl ether

(E)-(4-Oxo-2-butenyl)phosphonsaeure-diethylester

hexanal

Downstream raw materials:

1,3,5,8-unidecatriene

4,5-epoxy-2-decenal

C₃₁H₃₅NO₅

2-octen-1-al

Refernces

• 1、 Yamaguchi, Susumu,Fujiwara, Hidenori,Tashima, Ikukazu,Iwanaga, Daigo,Ushio, Hideki. "Effect of oxidized arachidonic acid and hexanal on the mouse taste perception of bitterness and umami". experimental part. p. 1884 - 1890. Retrieved 2011/06/17.
• 2、 Kann, Nina,Rein, Tobias,Akermark, Bjoern,Helquist, Paul. "New Functionalized Horner-Wadsworth-Emmons Reagents: Useful Building Blocks in the Synthesis of Polyunsaturated Aldehydes. A Short Synthesis of (+/-)-(E,E)-Coriolic Acid". . p. 5312 - 5323. Retrieved 2007/10/02.