4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate

Base Information

• Chemical Name: 4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate
• CAS No.: 99506-45-3
• Molecular Formula: BF₄*C₉H₁₈B₁₀IO
• Molecular Weight: 464.06
• Mol file: 99506-45-3.mol

Synonyms:4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate

Chemical Property of 4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate

There total 1 articles about 4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

tetrafluoroboric acid + (9-m-C2H2B10H9)iodosobis(trifluoroacetate) + methoxybenzene (100-66-3) → 4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate (99506-45-3)

Guidance literature:

With sulfuric acid; acetic anhydride; In water; acetic anhydride; acetic acid; dropwise addn. of H2SO4 to a mixture of carborane, anisole, Ac2O and CH3COOH (stirring, 0°C), pouring onto ice, washing with C6H6, addn.of 40% HBF4; extn. by 3:1 MeNO2-CHCl3, evapn. of exts. in vac, pptn. by ether, purifn. by repptn. from acetone by ether; elem. anal.;

DOI:10.1007/BF00948078

Reference yield: 100.0%

4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate (99506-45-3) + sodium chloride (7647-14-5) → 9-iodo-m-carborane (17157-02-7) + 9-chloro-m-carborane (17819-85-1) + para-iodoanisole (696-62-8) + methoxybenzene (100-66-3)

Guidance literature:

In chloroform; water; mixt. of aryl(m-carboran-9-yl)iodonium tetrafluoroborate, NaCl, water and chloroform was vigorously stirred under reflux at 56°C, 2-2.5 h; internal standard (chlorobenzene) added and org. layer was analysed by GLC;

Reference yield: 87.0%

4-methoxyphenyl(m-carboran-9-yl)iodonium tetrafluoroborate (99506-45-3) → 9-iodo-m-carborane (17157-02-7) + 9-hydroxy-1,7-dicarba-closo-dodecaborane (54360-42-8) + 9-nitro-m-carbaborane (114992-96-0) + para-iodoanisole (696-62-8) + methoxybenzene (100-66-3)

Guidance literature:

With sodium nitrite; In dichloromethane; water; mixt. of NaNO2 and the boron contg. salt in a two phase system stirred vigorously at 40°C, 3h (accompanied by evolution of nitrogen oxides), further product: C6H5NO2 (traces); organic layer sepd. from aq. layer, evapn. of CH2Cl2 in vac., residue sepd. by chromy. (silica gel, hexane (9-iodo-m-carbaborane); benzene-hexane 1:1 (9-nitro-m-carbaborane); ether (9-hydroxy-m-carbaborane);

upstream raw materials:

methoxybenzene

Downstream raw materials:

9-iodo-m-carborane

9-hydroxy-1,7-dicarba-closo-dodecaborane

9-nitro-m-carbaborane

para-iodoanisole