5,10,15-tri(p-tolyl)-20-(p-carboxyphenyl)porphyrin acid chloride

Base Information

• Chemical Name: 5,10,15-tri(p-tolyl)-20-(p-carboxyphenyl)porphyrin acid chloride
• CAS No.: 61449-64-7
• Molecular Formula: C₄₈H₃₅ClN₄O
• Molecular Weight: 719.285
• Mol file: 61449-64-7.mol

Synonyms:5,10,15-tri(p-tolyl)-20-(p-carboxyphenyl)porphyrin acid chloride

Chemical Property of 5,10,15-tri(p-tolyl)-20-(p-carboxyphenyl)porphyrin acid chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10,15-tri(p-tolyl)-20-(p-carboxyphenyl)porphyrin acid chloride

There total 4 articles about 5,10,15-tri(p-tolyl)-20-(p-carboxyphenyl)porphyrin acid chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5-(4-carboxyphenyl)-10,15,20-tris(4-methylphenyl) porphyrin (61449-63-6) → 5,10,15-tri(p-tolyl)-20-(p-carboxyphenyl)porphyrin acid chloride (61449-64-7)

Guidance literature:

With oxalyl dichloride; In dichloromethane; for 1h; Heating;

DOI:10.1021/ja00036a002

Reference yield:

5-(4-Carboxyphenyl)-10,15,20-tris(4-methylphenyl) porphyrin (61449-63-6) → 5-(p-benzoyl chloride)-10,15,20-tri(p-tolyl)porphyrin (61449-64-7)

Guidance literature:

With thionyl chloride; In benzene; for 3h; Heating;

Reference yield:

4-methyl-benzaldehyde (104-87-0) → 5,10,15-tri(p-tolyl)-20-(p-carboxyphenyl)porphyrin acid chloride (61449-64-7)

Guidance literature:

Multi-step reaction with 2 steps

1: propionic acid / 4 h / Reflux

2: pyridine; thionyl chloride / toluene / 3 h / Inert atmosphere; Reflux

With pyridine; thionyl chloride; In propionic acid; toluene;

DOI:10.1039/c002757j

upstream raw materials:

5-(4-Carboxyphenyl)-10,15,20-tris(4-methylphenyl) porphyrin

5-(4-carboxyphenyl)-10,15,20-tris(4-methylphenyl) porphyrin

4-methyl-benzaldehyde

Downstream raw materials:

N-{4-[(1E,3E,5E,7E,9E,11E,13E,15E,17E)-3,7,12,16-Tetramethyl-18-(2,6,6-trimethyl-cyclohex-1-enyl)-octadeca-1,3,5,7,9,11,13,15,17-nonaenyl]-phenyl}-4-((1Z,4Z,9Z,15Z)-10,15,20-tri-p-tolyl-porphyrin-5-yl)-benzamide

5-(p-benzoyloxypropyl 2-hydroxy-5-methoxyphenylacetate)-10,15,20-tri(p-tolyl)porphyrin

5-(p-benzoyloxypropyl 2,5-dimethoxyphenylacetate)-10,15,20-tri(p-tolyl)porphyrin

C₉₀H₁₀₄N₄O₃₆